As the acidity of the deep waters of the lake is high, and its CO2 content 
equally, I would suggest to add a large volume of fine-grained olivine. It will 
react fast with the CO2, converting it to bicarbonate solutions. This is the 
safest and quickest way to avert the danger of a sudden ebullition (like at 
lake Nyos in Cameroun, 1986, where 1800 people died by CO2 asphyxiation). In 
addition, when the CO2 is captured, and the pH of the lake raised, you also do 
something against climate change, Olaf Schuiling,

From: [email protected] [mailto:[email protected]] 
On Behalf Of Andrew Lockley
Sent: dinsdag 30 december 2014 11:32
To: geoengineering
Subject: [geo] Pilot plant for removal of extreme gas charges from deep waters 
-- ScienceDaily


Poster's note : this idea was discussed by Lockley in reference to control of 
methane emissions from water bodies. A methane pilot plant called Kivuwatt is 
in development or operation

http://www.sciencedaily.com/releases/2014/12/141218103217.htm?utm_source=feedburner&utm_medium=feed&utm_campaign=Feed%3A+sciencedaily%2Fstrange_science+%28Strange+%26+Offbeat+News+--+ScienceDaily%29

Pilot plant for removal of extreme gas charges from deep waters

December 18, 2014
Helmholtz Centre for Environmental Research - UFZ

Summary:
Being part of the mining area Herrerias, Andalusia, deep waters of Pit Lake 
Guadiana show extremely high concentration of dissolved carbon dioxide. In the 
case of a spontaneous ebullition, human beings close-by would be jeopardized. 
To demonstrate the danger and the possible solution, scientists constructed a 
pilot plant for degassing.

Being part of the mining area Herrerias in Andalusia, deep waters of Pit Lake 
Guadiana show extremely high concentration of dissolved carbon dioxide (CO2). 
In the case of a spontaneous ebullition, human beings close-by would be 
jeopardized. To demonstrate the danger and the possible solution, scientists of 
the Spanish Institute of Geology and Mining, the University of the Basque 
Country (UPV/EHU, Bilbao) and the Helmholtz Centre for Environmental Research 
(UFZ) constructed a pilot plant for degassing. A fountain pulls deep water 
through a pipe to the surface, where the gas can escape from the water. The 
buoyancy produced by the bubbles provides the energy required for driving the 
flow.

"The deep water in the residual lake Guadiana contains an extremely high volume 
of carbon dioxide (CO2). Oxidation of ores has created a very acidic milieu, 
which is also known from other mining areas. In the mining area Herrerias 
however, this acidity dissolves carbonate from the rocks and produces carbonic 
acid (dissolved CO2), which can be accumulated under the high pressures of deep 
waters in the lake. There is not much circulation beyond 25 meter depth to 
remove the gas load" says Dr. Bertram Boehrer of UFZ, who is physicist and has 
been investigating stratification in lakes at many places on Earth. Due to the 
high hydrostatic pressure, each liter of deep water contains about 2.5 liters 
of CO2 gas. As long as the stratification remains stable, the gas is retained 
in the deep water. A land slide or other processes producing large water 
movements could facilitate a sudden release of gas previously confined under 
high pressure. Inhaled air of 8 percent CO2 are considered deadly for 
humans.Now the scientists installed a degasing pipe which is the heart of the 
new pilot plant: Deep water enters a pipe at 61m depth. On the way up, 
hydrostatic pressure drops and gas bubbles form. The reduced density of the 
water-gas-mixture allows that deep water is pushed out of the pipe at the upper 
end to form a fountain above the water table, where gas is released to the 
atmosphere. This is an elegant solution, as the system does not require any 
additional driver, and the controlled release of CO2 does not pose any problem. 
"With this pilot plant, we could demonstrate that this approach also works in 
Guadiana pit lake. This can now be proposed to authorities as a possible 
approach to deal with the gas load." Though the lake in the mining area is 
fenced and access is not permitted to the public, this prohibition is difficult 
to survey.

Earlier installations in Lake Nyos in Cameroon served as a good example for 
this approach. In this lake, degassing pipes had been installed, which released 
the gas load with three fountains. On August 21st 1986, a large volume of gas 
escaped from the lake suddenly. The gas entered valleys of the surrounding 
area. 1700 human beings and thousands of animals were killed. The trigger could 
have been a land slide though this was never really proven. To avoid a 
repetition of this disaster, the gas load is slowly removed from the lake. One 
more crater lake called Monoun in Cameroon suffocated 37 human beings close to 
its shores in a similar eruption. Also in Monoun degasing fountains have been 
installed.In Guadiana pit lake we do not see the same danger as in Lake Nyos, 
due to smaller size and depth. In addition, a density gradient between surface 
waters and deep waters is keeping the system stable. However, gas 
concentrations are so high that precaution must be taken. More detailed 
investigations must be implemented and remediation must be considered, says Dr. 
Boehrer. For the formation of such extreme gas loads, lakes must be 
sufficiently deep with incomplete winter recirculation (meromixis) and a strong 
carbon dioxide source. At the moment, we do not have such a lake in

Source:The above story is based on materials provided by Helmholtz Centre for 
Environmental Research - UFZ. The original article was written by Tilo Arnhold. 
Note: Materials may be edited for content and length.

Journal Reference:

Javier Sánchez-España, Bertram Boehrer, Iñaki Yusta. Extreme Carbon Dioxide 
Concentrations in Acidic Pit Lakes Provoked by Water/Rock 
Interaction.Environmental Science & Technology, 2014; 48 (8): 4273 DOI: 
10.1021/es5006797
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