I strongly doubt that this is the solution to capture and store 35 billion tons 
of CO2 each year. Doing it the way nature has always done it (by reaction with 
basic silicates, a process called weathering), but speeding up the process by 
providing a larger reactant surface seems a more straightforward way to me, 
Olaf Schuiling

From: [email protected] [mailto:[email protected]] 
On Behalf Of Andrew Lockley
Sent: dinsdag 10 maart 2015 19:56
To: geoengineering
Subject: [geo] Alkali Metal Nitrate-Promoted High-Capacity MgO Adsorbents for 
Regenerable CO2 Capture at Moderate Temperatures - Chemistry of Materials (ACS 
Publications)


http://pubs.acs.org/doi/abs/10.1021/cm503295g

Alkali Metal Nitrate-Promoted High-Capacity MgO Adsorbents for Regenerable CO2 
Capture at Moderate Temperatures

Takuya Harada †, Fritz Simeon ‡, Esam Z. Hamad ‡, and T. Alan Hatton *†

Chem. Mater., Article ASAP
DOI: 10.1021/cm503295g
Publication Date (Web): March 3, 2015

[email protected]<mailto:[email protected]>.

Regenerable high capacity CO2 sorbents are desirable for the establishment of 
widespread carbon capture and storage (CCS) systems to reduce global CO2 
emissions. We report on the marked effects of molten alkali metal nitrates on 
CO2 uptake by MgO particles and their impact on the development of highly 
regenerable CO2 adsorbents with high capacity (>10.2 mmol g–1) at moderate 
temperatures (∼300 °C) under ambient pressure. The molten alkali metal nitrates 
are shown to prevent the formation of a rigid, CO2-impermeable, unidentate 
carbonate layer on the surfaces of MgO particles and promote the rapid 
generation of carbonate ions to allow the high rate of CO2 uptake.
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