http://epic.awi.de/38447/

The role of iron during the open ocean dissolution of olivine in a
simulated CO2 removal experiment — enhanced weathering, ocean
alkalinization, ocean fertilization

Köhler, P. , Hauck, J. , Völker, C. and Wolf-Gladrow, D. (2015): The role
of iron during the open ocean dissolution of olivine in a simulated CO2
removal experiment — enhanced weathering, ocean alkalinization, ocean
fertilization , Climate Engineering Research Symposium 2015, Berlin, 7 July
2015 - 10 July 2015 .

hdl:10013/epic.45795
[email protected]

Abstract:

One CO2 removal mechanism proposed as geoengineering approach is enhanced
silicate weathering. We here follow up on previous simulation experiments
on the open ocean dissolution of olivine, a well-distributed
magnesium-iron-silicate and focus on the role of iron. Olivine is known to
contain a magnesium:iron ratio of ~9:1. Iron is a micronutrient and in
various areas of the ocean marine biology is iron-limited. It is thus
expected that olivine dissolution as a large-scale geoengineering
application for CO2 removal would increase the iron input into the ocean
with implications for marine biology. With the numerical simulation of the
marine ecosystem and biogeochemistry model RECOM-2 embedded in the ocean
general circulation model MITgcm the potential changes in the marine
biological productivity via associated iron fertilization were analysed.
Since it is not clear how much of the iron contained in olivine will be
lost by colloid formation and aggregation before becoming biologically
available we show in sensitivity experiments that already the availability
of 0.1% of the iron enhances the oceanic carbon uptake connected with the
olivine dissolution by 20% compared to similar experiments in which the
effect of iron is neglected. Results saturate at an increase in marine
carbon uptake rate of 35% if 1% or more of the dissolved iron would be
biologically available. For an addition of 3 Pg/yr of olivine with a 1%
solubility the additional biologically available iron in the surface ocean
would be 2.4 Tg/yr, which is 10x larger than the dissolved iron input by
dust. The effect of such an iron fertilization would lead in certain areas
to species shifts in the phytoplankton communities with diatoms being one
of the winners and effects would be largest in the Southern Ocean.

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