http://cordis.europa.eu/result/rcn/161070_en.html

CARBFIX Report Summary
Project reference: 283148
Funded under: FP7-ENERGY
Final Report Summary - CARBFIX (Creating the technology for safe, long-term
carbon storage in the subsurface) [Print to PDF] [Print to RTF]
Executive Summary:
Members of the CarbFix project have over the past three years developed the
technology and expertise to capture, transport and geologically store CO2
as carbonate minerals through in-situ carbonation in the subsurface. This
knowledge has furthermore been demonstrated at the pilot scale at
Hellisheidi power plant, SW-Iceland, where a pilot gas separation station,
pipes for transport and injection and monitoring infrastructure was
successfully built and operated.
CarbFix differs from many current carbon storage projects in several
important aspects. First, it aims to provide a complete carbon capture,
transport and storage (CCS) solution at a single operating power-plant.
Second, in contrast to most projects, CarbFix aims at storing carbon by
accelerating the transformation of CO2 into stable carbonate minerals (e.g.
calcite) as rapidly as possible. Because calcite is stable over millions of
years, once CO2 is transformed into carbonate minerals, there is little
need for further monitoring. One can ‘walk away’ from the storage site.

To accelerate this transformation, CarbFix developed and adopted a unique
approach. Most subsurface carbon storage projects until now have injected
supercritical CO2 into large sedimentary basins (Figure 1 a). Recent work
has suggested that the transformation of CO2 to carbonate minerals in such
systems takes tens of thousands of years or more, if it occurs at all
(Figure 2). This is because of the slow reactivity of silicate minerals in
sedimentary rocks and the lack of the calcium, magnesium, and iron that are
necessary for making carbonate minerals. The alternative method developed
by CarbFix is to dissolve the CO2 in water prior to or during injection
into a basalt hosted reservoir to make it much more reactive with the
basaltic host rock (Figure 1 b).
Injection of carbon dioxide into basaltic rocks has several advantages.
First, approximately 25 weight percent of basalt is made of calcium,
magnesium, and iron oxides. Second, basaltic rocks are far more reactive
than sedimentary silicate rocks, meaning that the metals contained in
basalts are more readily available to combine with injected CO2 to form
carbonate minerals. Third, basaltic rocks are abundant on the Earth´s
surface with about 10% of the continents and much of the ocean floor
comprised of basalt. These advantages suggest that basalt carbonation could
be an important carbon storage solution for the future.

In this project, we have demonstrated that:

• Solubility trapping of CO2 occurs immediately
• Injected carbon is trapped in minerals within a few years using the
CarbFix injection method in basalt hosted storage reservoirs (Figure 1 b)

These results suggest that the CarbFix method can change the time scale of
mineral carbon trapping considerably.

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