http://onlinelibrary.wiley.com/doi/10.1002/anie.201507846/abstract;jsessionid=989BEBCF71FAE053FF8D6CB3F194BD00.f01t04
Capture CO2 from Ambient Air Using Nanoconfined Ion Hydration Authors Xiaoyang Shi, Hang Xiao, Prof. Klaus S. Lackner, Prof. Xi Chen First published:23 February 2016 DOI:10.1002/anie.201507846 Abstract Water confined in nanoscopic pores is essential in determining the energetics of many physical and chemical systems. Herein, we report a recently discovered unconventional, reversible chemical reaction driven by water quantities in nanopores. The reduction of the number of water molecules present in the pore space promotes the hydrolysis of CO32− to HCO3− and OH−. This phenomenon led to a nano-structured CO2sorbent that binds CO2 spontaneously in ambient air when the surrounding is dry, while releasing it when exposed to moisture. The underlying mechanism is elucidated theoretically by computational modeling and verified by experiments. The free energy of CO32− hydrolysis in nanopores reduces with a decrease of water availability. This promotes the formation of OH−, which has a high affinity to CO2. The effect is not limited to carbonate/bicarbonate, but is extendable to a series of ions. Humidity-driven sorption opens a new approach to gas separation technology. -- You received this message because you are subscribed to the Google Groups "geoengineering" group. To unsubscribe from this group and stop receiving emails from it, send an email to [email protected]. To post to this group, send email to [email protected]. Visit this group at https://groups.google.com/group/geoengineering. For more options, visit https://groups.google.com/d/optout.
