Dear Geoengineering group,


This post is to complete what Dr. Schuiling (mineral carbonation) and Dr. Salter (SRM by marine cloud brightening) said, and also to complete several previous remarks made by Dr. Rau saying that we can’t talk of CDR, ignoring ocean-based and/or abiotic negative energy systems +/- ocean C storage, as the oceans represent 70% of the Earth’s surface!



Any ranking has to consider not only the well-known cooling parameters, like SRM dependant albedo increase, CO2 depletion by assimilation, CO2 burial by BECCS but also the less discussed like methane depletion by enhancing the atmospheric oxidation or the CO2 increase by SRM dimming. Many examples of such alternative cooling parameters have been given by Gaïa before during the numerous Ice Ages on Earth by dust-induced cooling. Recent work shows that iron, an important component of air-borne mineral dust, has at least 12 cooling effects and, to our knowledge, is the only known one which acts both on the troposphere, the continents, the oceans and the sediments:



Troposphere

Iron salt aerosols accelerates the depletion of GHGs like methane and ozone and also the depletion of soot aerosols, by °Cl atom and °OH atom emission, Fenton oxidation and photo Fenton oxidation.

Also iron salt aerosols (ISA) increase cloud albedo: photocatalytic processes make the oxidic iron hygroscopic and enhance its iron solubility. This enhances the aerosols transparency, makes it lighter colored and provides it with an enhanced cloud condensation affinity.

SO2, NOx and organic emissions from natural sources or from anthropogenic ones, generate sulfuric, nitric and organic acids. These acids transform sea salt spray into HCl and accelerate photolytic °Cl atom generation from ISA. Also NOx accelerates the photolytic °Cl atom production by ISA.



Oceans

Iron salt aerosols activates the CO2 assimilation of phytoplankton by micronutrient fertilization. Phytoplankton blooms emit DMS and chloro-organic molecules. Their oxidation products increase the cloud albedo.

H2SO4 (from DMS oxidation) further increases the chlorine ISA-induced methane (and VOC) depletion by HCl generation from sea-spray.



Continents and sediments

Iron salt aerosols deposition acts as a micro-nutrient fertilizer on plants suffering from chlorosis (iron deficiency) and increase the CO2 assimilation and the plant-induced CO2 weathering to HCO3-

The desert varnish build up by ISA induces methane and ozone-depletion.

Last but not least, methane consuming microbes within iron-poor environments like peat bogs, wetlands, sediments and thawing permafrost, are activated by ISA, and methane producing micro-organisms are inhibited: the result is a reduction of the methane emissions from these environments.



To our knowledge the Iron salt aerosols method proposed <http://www.earth-syst-dynam.net/8/1/2017/esd-8-1-2017.pdf> is the only yet proposed CE method which natural equivalent during the paleo climates during the glacial times has been verified numerous times. This verification includes all kinds of properties of the ISA method, not only its many CE cooling activities, it includes its influences on the marine and continental ecosystems.



The natural ISA method equivalent is the iron containing mineral dust blown off in high emission rates from dry grounds with low vegetation cover during the glacial time. This fruitful loess soil building dust cooled up to 9 °C the global climate during glacial time climate by the same mechanisms. Like the ISA method this natural cooling mechanism used only the ingredients dust, sunshine and sea-spray to generate the climate cooling.

In comparison to its natural equivalent, the “Iron salt aerosols method <http://www.earth-syst-dynam.net/8/1/2017/esd-8-1-2017.pdf>” needs only to stop further climate warming and a global climate cooling of 1 °C in maximum.



The ISA method acts only within the lower part of the troposphere (not in the stratosphere). This allows:

· regional restriction of the ISA method to regional parts of the planet’s surface;

· easy process control by enlarging or reducing the ISA covered surface

· immediate stop when the desired climate temperature has been achieved

· reduction of possible negative influences on ecosystems (like cloud albedo increase on regional parts of the Earth surface)



The iron salt aerosols method is cheap, feasible, and is already occurring (some scientist think anthropogenic emissions of soluble bio-available iron already have increased the marine productivity up to 50% in some regions, compared to pre-industrial era), it only needs to be enhanced.



Like Dr. Eisenberger and Dr. Cady, we look forward for a scoring system able to perform an independent and honest comparison of the ISA method, towards other GHGR, CDR and SRM methods. Hopefully, the GeoMIP might be able to perform it!



Best regards,

Franz Dietrich Oeste


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