http://onlinelibrary.wiley.com/doi/10.1002/2017JD027006/abstract

Radiative and chemical response to interactive stratospheric sulfate
aerosols in fully coupled CESM1(WACCM)
Authors

   - Michael J. Mills,
   - <[email protected]>
      - <http://orcid.org/0000-0002-8054-1346>
   1.
   -

      <[email protected]>

   
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   - Jadwiga H. Richter,
   - <http://orcid.org/0000-0001-7048-0781>
   1.

   
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   - Simone Tilmes,
   - <http://orcid.org/0000-0002-6557-3569>
   1.
      2.

   
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   - Ben Kravitz,
   - <http://orcid.org/0000-0001-6318-1150>
   1.

   
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   - Douglas G. MacMartin,
   - <http://orcid.org/0000-0003-1987-9417>
   1.
      2.

   
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   - Anne A. Glanville,
   1.

   
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   - Joseph J. Tribbia,
   - <http://orcid.org/0000-0003-1639-9688>
   1.

   
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   - Jean-François Lamarque,
   1.
      2.

   
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   - Francis Vitt,
   - <http://orcid.org/0000-0002-8684-214X>
   1.

   
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   - Anja Schmidt,
   - <http://orcid.org/0000-0001-8759-2843>
   1.
      2.
      3.

   
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   - Andrew Gettelman,
   - <http://orcid.org/0000-0002-8284-2599>
   1.
      2.

   
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   - Cecile Hannay,
   1.

   
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   - Julio T. Bacmeister,
   1.

   
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   - Douglas E. Kinnison
   - <http://orcid.org/0000-0002-3418-0834>
   1.

   
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   - Accepted manuscript online:6 November 2017Full publication history
   
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   - DOI:10.1002/2017JD027006  View/save citation
   
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   - This article has been accepted for publication and undergone full peer
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   and proofreading process, which may lead to differences between this
   version and the Version of Record. Please cite this article as doi:
   10.1002/2017JD027006

Abstract

We present new insights into the evolution and interactions of
stratospheric aerosol using an updated version of the Whole Atmosphere
Community Climate Model (WACCM). Improved horizontal resolution, dynamics,
and chemistry now produce an internally generated quasi-biennial
oscillation, and significant improvements to stratospheric temperatures and
ozone compared to observations. We present a validation of WACCM column
ozone and climate calculations against observations. The prognostic
treatment of stratospheric sulfate aerosols accurately represents the
evolution of stratospheric aerosol optical depth and perturbations to solar
and longwave radiation following the June 1991 eruption of Mt. Pinatubo. We
confirm the inclusion of interactive OH chemistry as an important factor in
the formation and initial distribution of aerosol following large inputs of
sulfur dioxide (SO2) to the stratosphere. We calculate that depletion of OH
levels within the dense SO2 cloud in the first weeks following the Pinatubo
eruption significantly prolonged the average initial e-folding decay time
for SO2 oxidation to 47 days. Previous observational and model studies
showing a 30-day decay time have not accounted for the large (30-55%)
losses of SO2 on ash and ice within 7-9 days post-eruption, and have not
correctly accounted for OH depletion. We examine the variability of aerosol
evolution in free-running climate simulations due to meteorology, with
comparison to simulations nudged with specified dynamics. We assess
calculated impacts of volcanic aerosols on ozone loss with comparisons to
observations. The completeness of the chemistry, dynamics, and aerosol
microphysics in WACCM qualify it for studies of stratospheric sulfate
aerosol geoengineering.

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