Poster's note: via David Keith, who questioned SRM implications

https://www.scientificamerican.com/article/an-underappreciated-danger-of-the-new-space-age-global-air-pollution/

An Underappreciated Danger of the New Space Age: Global Air Pollution
As private launches increase dramatically, so will emissions of CO2,
particulates and other noxious substances

By Martin N. Ross, Leonard David on November 6, 2020
An Underappreciated Danger of the New Space Age: Global Air Pollution
A SpaceX Falcon 9 rocket launches into space. Credit: Getty Images

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The space industry is growing and innovating at a pace not seen since the
days of the moon landings. Fifty years ago, nearly everything related to
space was a government-sponsored project. In 21st-century space, launch
vehicle and satellite finance are most often bottom-line corporate
investments or public-private partnerships.


Untethered from government leashes, the global space industry looks and
operates increasingly like global aviation. Reusability. Regular flight
cadence. Mass production of spacecraft and launch vehicles. Analysts
predict that the space industry’s contribution to global GDP could cross
the 1 percent threshold by 2040. We can reasonably construct future
scenarios where the space and aviation industries have comparable economic
clout.

A great deal of aviation’s remarkable airframe and propulsion developments
since World War II have been guided by sustainability concerns, mainly
focused on jet engine emissions. Modern jet engines emit much less soot and
gas pollutants than engines emitted 50 years ago. The pressure to reduce
jet emissions has been good for aviation because honing turbine combustion
to near theoretical maximum efficiency has had the benefit of reducing fuel
consumption. Good for corporate bottom lines, and good for the Earth.


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Sustainability has not much been a concern for space systems development.
Just like their jet engine cousins, rocket engines emit a variety of gases
and particles into the atmosphere that can have regional and even global
consequences. Even so, launch vehicle environmental impacts are typically
disregarded by comparing jet and rocket fuel consumption in an overly
simplified way.

The argument goes like this: Rockets burn only 0.1 percent of the fuel that
aircraft burn each year and are therefore only 0.1 percent of the emissions
problem that aviation presents. But this is a case of false equivalence.
Careful understanding of every phase of space flight shows that space
emissions can impact the atmosphere in ways that are wholly different from,
and in some cases larger than, aviation emissions.

Unlike with aviation, every layer of the atmosphere sees space industry
emissions. While jet emissions into the troposphere are quickly washed away
to the surface by precipitation, rocket emissions into the stratosphere
clean away only slowly. Stratospheric emissions accumulate year over year,
adding up exhaust from all of Earth’s launches and reentries over the past
four or five years. In fact, the fragile ozone layer resides in the
stratosphere, near where rocket emissions accumulate.

Prospects for space travel have never been more thrilling. Space industry
advances, including high-performance smallsats, low-Earth-orbit
megaconstellations, new rocket propellants, and lunar resource extraction,
are driving the 21st-century New Space growth. Expectations are high that
these developments will bring forth the long-held ambition to make space
travel as commonplace as air travel. But are these new space technologies
on path of sustainable growth?

GAS EMISSIONS FROM ROCKETS


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Rocket engine exhaust, like jet exhaust, is mostly carbon dioxide and water
vapor and the global impacts of these emissions are well understood. Carbon
dioxide emitted at any altitude is a “long-lived” greenhouse gas (GHG),
adding to the atmospheric GHG burden. Water vapor is a “short-lived” GHG.
The global impacts of these components of rocket exhaust are small, a
fraction of a percent of aviation’s CO2 and H2O global impacts. Even though
the major components of rocket engine exhaust have no significant global
impacts, some specific minor components require closer inspection.

Solid rocket motor (SRM) oxidizer, ammonium perchlorate, contains chlorine,
the most serious threat to stratospheric ozone. Direct plume sampling 20
years ago by NASA aircraft showed that SRM plumes create dramatic ozone
“miniholes” that persist for several days after a launch. The miniholes
disappear however as the chlorine-laden plumes mix into the global
stratosphere, and all the chlorine emitted by SRMs each year is small and
short-lived compared to the chlorine released by the notorious
chlorofluorocarbons. Chlorine from SRMs is most likely not a serious threat
to the ozone layer.

Scientists well understand how the CO2, H2O and Cl gas emissions from
rockets affect climate and ozone. And all this research indicates that
these impacts are insignificant compared to other pollution sources and
buried in the noise of the global atmosphere. Even if these launch
emissions increased by an order of magnitude, their impacts would be small.
However, there is another component to rocket exhaust that could be
significant: particles of soot (black carbon) and alumina (Al2O3).

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PARTICLE EMISSIONS

Rockets famously display brilliant exhaust plumes. Hydrocarbon-fueled
rocket engine “flame” is mostly the incandescent glow of soot particles
oxidizing in the hot plume. Soot production in rocket engines is
complicated and not very well understood. Soot forms in fuel-rich
combustion chambers, fuel-cooling nozzle walls and turbopump gas
generators, and is partly consumed in the hot plumes. Jet engines have none
of these complexities and burn very clean compared to rocket engine. Some
types of hydrocarbon-fueled rocket engines emit hundreds of times more soot
for each kilogram of fuel burned than do their jet engine cousins. And jets
only occasionally fly in the stratosphere; rockets fly there every launch.


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What is the concern about soot in the stratosphere? Black carbon soot (BC)
very efficiently absorbs sunlight. The absorbed energy is transferred to
surrounding air so that BC acts as a heat source, warming the stratosphere,
which can in turn slightly change the circulation of the global atmosphere.
And since ozone concentration is inversely proportional to temperature, a
warmer stratosphere equates to depletion of the ozone layer. Is the BC
emitted by the current global fleet of rockets great enough to have a
significant impact on the global atmosphere? We do not yet know. The
required climate models are only now being assembled. BC soot emission by
hydrocarbon-fueled rockets, and its global impacts remain a mystery.

SRM plumes are even more brilliant than hydrocarbon-fueled plumes. White
hot alumina droplets leaving the nozzle are the source for the SRM “flame.
As with the chlorine gas emission, SRM plumes diffuse and eventually mix
into the global atmosphere so that rocket alumina particles are found in
random stratospheric air samples from equator to poles. In the 1990s,
researchers discovered how ozone-destroying chemical reactions occur on the
surface of SRM alumina particles, but alumina’s significance as a source of
ozone depletion is not known. SRMs emit ozone-destroying chlorine gas, too,
of course, and the double-sided nature of SRM ozone depletion remains
poorly described. The 2018 World Meteorological Organization (WMO) Ozone
Assessment acknowledged the large knowledge gaps and noted that further
research is "warranted."

The space shuttle SRMs were the largest ever flown, and it is often
mistakenly assumed that the use of large solid rockets ended when the space
shuttle retired. In fact, SRMs are finding increasing launch applications
around the planet. The Space Launch System’s 144-inch diameter SRMs will be
the most massive ever flown. Even SLS will be eclipsed by a Chinese
156-inch SRM planned for 2025 debut. SRMs present a growing and poorly
known hazard to stratospheric ozone.

NOT ONLY LAUNCH

Contrary to many media stories about the latest space junk reentry
spectacular, space junk returning to Earth does not “disappear” upon
reentry. Some parts of derelict spacecraft will survive reentry and reach
the surface. However, most of the reentering mass vaporizes into a hot gas
that quickly condenses into a spray of small particles. Thus, as with
launch, bright plumes mean particle production. Unlike the chemically
simple particles from launch, particles from reentering space junk will be
a zoo of complex chemical types. Particles from vaporizing propellant
tanks, computers, solar panels and other exotic materials will form around
an 85-kilometer altitude then drift downward, accumulating in the
stratosphere along with launch’s soot and alumina. Reentry is as much of an
“emission” as launch.


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The growing LEO megaconstellations, with thousands of satellites in each
constellation, use reentry vaporization as the satellite end-of-life
disposal mechanism. Once these constellations are deployed, hundreds of
tons of nonfunctioning satellites will be “brought in” for disposal every
year. Most of this mass will become particles in the middle atmosphere.
Very little is known about reentry dust production, the microphysics of the
particles and how reentry dust could affect climate and ozone.

SUSTAINABLE SPACE

Space has entered a growth phase reminiscent of aviation’s early days. Once
a technology becomes normalized into the market economy, there is no limit
to potential new applications. And like its aviation industry big brother,
the space industry emits gases and particles into the atmosphere from
propulsion systems. But a comparison between aviation emissions and space
emissions must account for the vastly different ways that the two
industries affect the Earth’s atmosphere.

CO2 emissions from jet engines will be much larger than CO2 emissions from
rocket engines for any foreseeable future. This is reflected in
well-meaning but misguided calculations of a conventional “carbon
footprint” for space. But CO2 is not where the action is for space
pollution. The particles emitted by rocket launches and space debris
reentries cause much larger changes in atmospheric chemistry, dynamics and
radiation than rocket CO2 emissions. For the space industry, the “carbon
footprint” is a complicated story that is yet to be appropriately defined.

The recent controversy over the brightness of LEO satellites illustrates
like a spotlight how sustainability needs to become a fundamental aspect of
space system development. It will be easier to guarantee unimpeded use of
space systems if the environmental impacts of every stage in a system’s
life cycle are evaluated ahead of time. This is how aviation contemplates
sustainability. Environmental concerns that appear after deployment
encourages regulation. Full and complete analysis before deployment
inoculates against regulation.


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Ironically, only space can provide the global perspective required to
manage humanity’s stewardship of the Earth. Apollo 8’s view of Earthrise is
often associated with the beginning of global environmentalism. And yet
space industry emissions themselves are too poorly known to answer
fundamental questions about space’s global impacts and sustainability.
Space has some work to do regarding environmental impacts. Looking to
aviation, an appropriate scientific program would include measurements of
launch and reentry plumes, detailed modeling of plumes from fresh emissions
to steady state global mixing, and laboratory measurements of the
microphysics of all the different particle types generated from launch to
reentry. The effort would be a government and commercial partnership.

The space industry is poised to become a more significant part of the
global economy just at a time when sustainability is becoming a common goal
across the economy. What would a sustainable space industry look like? What
are the future regulatory threats to space development? We will not know
the answers to these questions until a sustained program scientific
research program, globally coordinated, on space industry emissions is
carried out.

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ABOUT THE AUTHOR(S)
Martin N. Ross
Martin N. Ross, Ph.D., is a scientist with The Aerospace Corporation who
leads research to further understand how aerospace propulsion systems
impact the Earth's atmosphere. He most recently coauthored (with Darin W.
Toohey) The Coming Surge in Rocket Emissions in EOS and served as a
coauthor on the 2018 WMO Scientific Assessment of Ozone Depletion.

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