https://agupubs.onlinelibrary.wiley.com/doi/full/10.1029/2024GL108314

*Authors*
Daniele Visioni, Ilaria Quaglia, Isabelle Steinke

*First published: 24 May 2024*

https://doi.org/10.1029/2024GL108314

*Abstract*
There are obstacles in better understanding the climate impacts associated
with new materials that could be used for Stratospheric Aerosol Injections
(SAI), like the lack of an integrated framework that combines climate
modeling across scales, laboratory studies and small-scale field
experiments. Vattioni et al. (2023, https://doi.org/10.1029/2023gl105889)
explored one aspect of using alternative, non-sulfate materials for SAI.
They investigated how uncertain the response of stratospheric ozone would
be to alumina injections for SAI. In their study, they quantify chlorine
activation rates in the presence of alumina, and then cascade these
uncertainties into estimates of ozone depletion, concluding that alumina
might have less detrimental impacts on stratospheric chemistry than
sulfate, but with large uncertainties. Their results provide a useful basis
upon which future research endeavors combining indoor and outdoor
experiments and modeling may be structured to produce robust assessments of
SAI impacts, benefits and uncertainties, together with clarifying what kind
of research needs to be prioritized.

*Key Points*
•Vattioni et al. (2023, https://doi.org/10.1029/2023gl105889) demonstrated
large uncertainties in the projected impacts of alumina particles in the
stratosphere

•We use the results to discuss more broadly how to better think about the
climate impacts and side effects of Stratospheric Aerosol Injection

•We propose the idea of a “living assessment” of Stratospheric Aerosol
Injections that can constantly integrate useful experimental results with
modeling work

*Plain Language Summary*
We could use tiny particles injected into the higher atmosphere to reflect
a small portion of incoming sunlight and thereby cool the planet. But doing
so comes with risks and uncertainties: for instance, one might wonder how
do we select which kind of particles to use. Sulfate is present in nature,
for instance during the aftermath of volcanic eruptions followed by an
observable surface cooling. However, we know that mimicking that effect
would come with some drawbacks, for example, it heats the upper layer of
the atmosphere and affects ozone. Alumina, supposedly, would impact
atmospheric chemistry less than sulfate and so might be considered
“preferable,” but not being naturally present in the atmosphere, there are
lots of things we don't know. For example, Vattioni et al. (2023,
https://doi.org/10.1029/2023gl105889) demonstrate that even potential
implications for atmospheric chemistry are highly uncertain when looking at
alumina particles as a candidate for Stratospheric Aerosol Injections
(SAI). Therefore, their study is a good opportunity to think more broadly
about intended SAI-associated climate impacts and unwanted side effects,
and how to better coordinate research activities in this space.


[image: Details are in the caption following the image]
<https://agupubs.onlinelibrary.wiley.com/cms/asset/e813d7a8-6719-40cd-9622-61c0a10fad4b/grl67611-fig-0001-m.jpg>
Figure 1

(a) A simplified summary of the results in Vattioni et al. (2023
<https://agupubs.onlinelibrary.wiley.com/doi/full/10.1029/2024GL108314#grl67611-bib-0022>),
focusing on tropical ozone changes. For SO2 (red dot), an uncertainty bar
derived using multi-model results from Tilmes et al. (2022
<https://agupubs.onlinelibrary.wiley.com/doi/full/10.1029/2024GL108314#grl67611-bib-0021>)
has been added, even if the injection magnitude are higher in that case.
(b) Schematic of potential uncertainty ranges that would be associated with
sulfate or alumina (or other materials) in the case of SAI for both
effectiveness and environmental impacts. Due to the lack of natural
analogs, physical and environmental uncertainties might be larger for
alumina compared to sulfate, but with the potential for the central value
to be lower for a close to ideal material, as shown in panel (a). Some
uncertainties can be narrowed down with further observations, or with
direct tests. Scenario uncertainty, which depends on factors that might not
be related directly to chemistry or physics, such as the underlying
emission scenario of ozone depleting substances, or other sources that are
not within direct control, and that require more holistic assessments, are
also relevant to an overall assessment.

*Source: AGU*

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