https://pubs.acs.org/doi/10.1021/acsami.5c16677

*Authors: *Tianbao Wu, Xueping Fan, Chao Wang, Guozhi Jia

*29 October 2025*

*Abstract*
For effective solar radiation management, windows in sustainable buildings
need to feature high visible light transmittance to support daylighting
needs, block unwanted solar radiation, and maintain an appropriate
photothermal performance. However, materials with a high photothermal
performance usually do not exhibit favorable light transmittance. Here, the
selectively transparent photothermal tannic acid-grafted Cu1.95S and MoS2
heterojunction (Cu1.95S/TA-MoS2) was prepared with a mild one-pot
synthesis. On the one hand, TA not only grafts both MoS2 and Cu1.95S but
also effectively absorbs ultraviolet light. On the other hand, the
incorporation of Cu1.95S enhances near-infrared absorption. The selectively
transparent photothermal membrane was fabricated by blending
Cu1.95S/TA-MoS2 with poly(vinyl alcohol). Compared with the TA-MoS2
membrane, the Cu1.95S/TA-MoS2 membrane achieved a 25.3% reduction in solar
transmittance with only a 6.3% loss in luminous transmittance. Moreover,
via Cu1.95S with localized surface plasmon resonance properties and a
synergistic effect with MoS2, the photothermal equilibrium temperature of
the Cu1.95S/TA-MoS2 membrane was increased by 23.4 °C. The membrane
demonstrates effective antifogging capability and generates a stable
voltage of 0.14 V when integrated with thermoelectric modules. This work
provides solid support for next-generation solar radiation management in
building windows.

*Source: ACS Publications*

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