https://www.science.org/doi/10.1126/sciadv.adw6526

*Authors: *Yaowei Li, John A. Dykema, David A. Peterson, Xu Feng, Xiaoli
Shen, Nicole A. June, Michael D. Fromm, et al.

*10 December 2025*

DOI: 10.1126/sciadv.adw6526


*Abstract*
Large wildfires can generate pyrocumulonimbus (pyroCb) clouds, injecting
massive quantities of smoke aerosols into the upper troposphere and lower
stratosphere (UT/LS), where they persist for months and affect climate. The
radiative effects of pyroCb aerosols, however, remain poorly understood
because of limited direct measurements. Here, we present in situ aircraft
measurements of 5-day-old pyroCb smoke, addressing a critical observational
gap in aerosol evolution from freshly emitted to weeks-to-months-aged
states. The sampled smoke primarily contained unusually large aerosol
particles (500 to 600 nanometers in diameter), formed through cloud
processing and efficient coagulation in the UT/LS. Compared to smaller
particles in typical non-pyroCb smoke, these large particles increase
outgoing radiation by 30 to 36%, substantially enhancing atmospheric
radiative cooling. Climate models may greatly underestimate this cooling
effect by assuming smaller aerosol sizes for pyroCb smoke. As pyroCb events
become more frequent, accurately representing their aerosol properties is
essential for improving climate projections.

*Source: Science Advances*

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