I have read that some believe the majority of the "waste" heat is a product of 
blacktop roads, roofs, etc., which absorb a broad range of frequencies and 
re-radiate it at much lower frequency band.  If that is the case(?), a simple 
white paint with correctly selected constituent elements, For Example-whitewash 
as specified in NASA specifications for painting shelters of temperature 
measuring thermometer; would reflect most of the incoming rays and not store 
them as blacktop roads and black roofs apparently do and re-radiate them as 
much lower frequencies. Thus, the white surface would send most of the heat 
back into space. As a test, just feel a car painted pure white and compare that 
to a black pointed car; but be careful on a bright, sunny day re burning of 
hand, especially in southern US or even closer to equator!  However, paint 
selection would be subject to NOT making a slick surface on roads, that would 
be disastrous, especially in rainy conditions.  Also,glare might prove very 
limiting.

> Date: Sat, 6 Jun 2009 09:08:23 -0700
> Subject: [Global Change: 3221] Re: Why not rooftops covered with infrared 
> LEDs? an abstract in IEEE  suggested ....
> From: [email protected]
> To: [email protected]
> 
> 
> I don't have the full paper either; perhaps someone reading here does
> have IEEE access, or knows where this was discussed if it was.
> 
> On the microcosm, the reason is to rapidly remove heat from a
> spacecraft by radiating it away.  The ISS uses big flat radiator
> panels rather than a 'cooling laser' because they can afford the huge
> surface area required -- on the global scale, to emit through the
> atmosphere would require wavelength control.
> 
> I suppose the same question applies to painting roofs white -- all the
> energy of making and applying the paint or new roofing material could
> be used differently too.
> 
> Heat that's already at the infrared level is mostly waste now, hard to
> scrape it up somehow into thermodynamically useful energy.  Can a
> range of infrared be captured and used to emit in an IR window band?
> 
> Some infrared photovoltaic material is being worked on
>  http://www.google.com/search?q=infrared+photovoltaic
> 
> 
> Maybe there'd be a way to use that kind of material to tune the
> wavelength and re-emit IR in a window band.
> 
> That's what led me to wonder about using roofing material rather than
> giant lasers -- the roofs have to be replaced every few decades
> anyhow, whether with bright white or with something that is bright in
> one of the IR windows.
> 
> Hey, it's science fiction --  the idea is to get rid of low-value heat
> by getting it collected in a wavelength that will exit through "IR
> window" bands.
> 
> A 'rogue wave' material -- something that from time to time will
> collect enough energy from all the lower waves around it into one
> larger wave tuned for the IR window. Paint or roofing material that
> glows or sparkles in IR window frequencies when it gets warm.
> http://scholar.google.com/scholar?q=%22Nature+Materials%22++infrared+photovoltaic
> 
> Of course the IR astronomers working in those windows would hate the
> idea.
> 
> Hell, the visible light astronomers are going to hate the idea, now
> that I look into it.
> 
> You've seen the huge blindingly bright LED billboards now going up
> along freeways?
> 
> Imagine what the advertisers are going to do with sprayable paint-on
> LEDs (sigh).
> http://www.nature.com/nmat/journal/v8/n6/abs/nmat2459.html
> 
> > 

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