>I would assume this is in an RFC somewhere. Anyone know where?

FWIW, here's the list of valid characters:

         
!#$%&'*+-/0123456789=?ABCDEFGHIJKLMNOPQRSTUVWXYZ^_`abcdefghijklmnopqrstuvwxyz{|}~

That's uppercase/lowercase letters, numbers, and the following characters:

         !#$%&'*+-/=?^_`{|}~

That's according to RFC821 page 31.  RFC822 allows for any "atext" 
(undefined) characters, or any a single quoted "qcontent" (again, 
undefined).  Note that the % character is used in addressing, so it won't 
be valid in an address.  Likewise, some other characters may be interpreted 
in some unexpected way, or break some programs.

                                                    -Scott
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