Public release date: 9-Jan-2005
http://www.eurekalert.org/pub_releases/2005-01/uot-nnp010705.php

Contact: Sonnet L'Abb�
[EMAIL PROTECTED]
416-978-0260
University of Toronto

Nanotechnologists' new plastic can see in the dark

Imagine a home with "smart" walls responsive to the environment in the room,
a digital camera sensitive enough to work in the dark, or clothing with the
capacity to turn the sun's power into electrical energy. Researchers at the
University of Toronto have invented an infrared-sensitive material that
could shortly turn these possibilities into realities.

In a paper to be published on the Nature Materials website Jan. 9, senior
author Professor Ted Sargent, Nortel Networks � Canada Research Chair in
Emerging Technologies at U of T's Department of Electrical and Computer
Engineering, and his team report on their achievement in tailoring matter to
harvest the sun's invisible rays.

"We made particles from semiconductor crystals which were exactly two, three
or four nanometres in size. The nanoparticles were so small they remained
dispersed in everyday solvents just like the particles in paint," explains
Sargent. Then, they tuned the tiny nanocrystals to catch light at very short
wavelengths. The result � a sprayable infrared detector.

Existing technology has given us solution-processible, light-sensitive
materials that have made large, low-cost solar cells, displays, and sensors
possible, but these materials have so far only worked in the visible light
spectrum, says Sargent. "These same functions are needed in the infrared for
many imaging applications in the medical field and for fibre optic
communications," he says.

The discovery may also help in the quest for renewable energy sources.
Flexible, roller-processed solar cells have the potential to harness the
sun's power, but efficiency, flexibility and cost are going to determine how
that potential becomes practice, says Josh Wolfe, managing partner and
nanotechnology venture capital investor at Lux Capital in Manhattan. Wolfe,
who was not part of the research team, says the findings in the paper are
significant: "These flexible photovoltaics could harness half of the sun's
spectrum not previously accessed."

Professor Peter Peumans of Stanford University, who has reviewed the U of T
team's research, also acknowledges the groundbreaking nature of the work.
"Our calculations show that, with further improvements in efficiency,
combining infrared and visible photovoltaics could allow up to 30 per cent
of the sun's radiant energy to be harnessed, compared to six per cent in
today's best plastic solar cells."

U of T electrical and computer engineering graduate student Steve MacDonald
carried out many of the experiments that produced the world's first
solution-processed photovoltaic in the infrared. "The key was finding the
right molecules to wrap around our nanoparticles," he explains. "Too long
and the particles couldn't deliver their electrical energy to our circuit;
too short, and they clumped up, losing their nanoscale properties. It turned
out that one nanometer � eight carbon atoms strung together in a chain � was
'just right'."

###

Other members of the U of T research team are Gerasimos Konstantatos, Shiguo
Zhang, Paul W. Cyr, Ethan J.D. Klem, and Larissa Lavina of electrical and
computer engineering; Cyr is also with the Department of Chemistry. The
research was supported in part by the Government of Ontario through
Materials and Manufacturing Ontario, a division of the Ontario Centres of
Excellence; the Natural Sciences and Engineering Research Council of Canada
through its Collaborative Research and Development Program; Nortel Networks;
the Canada Foundation for Innovation; the Ontario Innovation Trust; the
Canada Research Chairs Program; and the Ontario Graduate Scholarship.




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