Hi John 

I did not remember about this command. but it should work
http://chemapps.stolaf.edu/jmol/docs/#bondorder

>     substituted "connect (all) (all) single modify" and got the desired 
> single bond.

If you need to change to this command, I suggest that you use a more 
specific one:

connect (carbon) (carbon) single
(with this you don't need to select the carbons before and also it will not 
affect other atoms)

>     Is this expected behavior?

No. It does seem like a bug in that version of Jmol. Bob will confirm that 
issue.



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