Chinese scientists’ quantum study hailed as a ‘breakthrough of the year’

Physics World puts creation of the world’s first ultracold three-atom molecules 
in top 10 scientific achievements of the year

The accolade comes days after the researchers unveiled their latest findings, 
expected to shed new light on how chemicals behave at the quantum level

By Ling Xin in Beijing Published: 6:00pm, 8 Dec, 2022

https://www.scmp.com/news/china/science/article/3202526/chinese-scientists-quantum-study-hailed-breakthrough-year?module=live&pgtype=homepage


Chinese scientists are ending the year with a double celebration. Days after 
releasing details of their latest breakthrough, a team from Anhui in eastern 
China has been included in Physics World’s top 10 achievements of 2022.

The researchers, from the University of Science and Technology of China (USTC), 
were recognised for their initial study earlier this year, which outlined 
indirect evidence that they had created the first ultracold three-atom 
molecules.

In their latest paper, published last Friday by the journal Science, the team 
confirmed the breakthrough which is expected to shed new light on how chemicals 
behave at the quantum level.

And on Tuesday, the Institute of Physics’s membership journal listed their 
first study – published in the February edition of Nature – as one of its top 
10 scientific breakthroughs of the year.

In their most recent study, the USTC researchers produced around 4,000 gas 
molecules, each containing one sodium-23 atom and two potassium-40 atoms, at 
100 nanokelvins – less than one millionth of a degree above absolute zero.

The achievement could help simulate chemical reactions, design new materials 
and even lead to a better understanding of the notoriously complex three-body 
problem.

“In the past two decades, researchers have used two atoms to make ultracold 
molecules. Our work took that to three, which is a first step towards 
assembling poly-atomic ultracold molecules,” said the paper’s co-author Zhao 
Bo, from the University of Science and Technology of China (USTC) in Hefei, 
Anhui province.

The paper’s reviewers hailed the study as a “milestone” in ultracold chemistry, 
a field in which atoms and molecules are cooled to extremely low temperatures 
to observe how they behave in slow motion, as well as how chemical reactions 
occur at the quantum level.

“Complex physics systems, including most chemical reactions, are very difficult 
to calculate even with the most powerful computers. Since ultracold atoms and 
molecules are highly controllable, we can use them to create an ideal complex 
system and study how it works,” Zhao said.

Zhao explained that by precisely measuring the structure, energy levels and 
other properties of three-atom molecules, researchers hope to provide 
observational evidence for the modelling and theoretical interpretations of the 
three-body problem in the quantum world.

The three-body problem seeks to establish the subsequent motion of three masses 
from their initial positions and velocities, according to Newton’s laws of 
motion and universal gravitation.

The first example of the problem to receive extended study was in astronomy and 
involved the Earth, moon and sun. No general solution to the problem is 
believed to be possible, because the motion of more than two bodies quickly 
becomes chaotic, a situation which is even more complex at the quantum level.

While scientists have long been able to chill atoms with lasers to within 
billionths of a degree above absolute zero, cooling molecules in the same way 
is much more challenging.

As light particles from a laser beam are absorbed and then re-emitted by atoms, 
they lose some kinetic energy and cool down. However, molecules are less 
responsive to laser beams because they are heavier. They also need to have the 
right internal structure to trigger the absorption and re-emission process.

One solution is to use ultracold atoms as building blocks to assemble ultracold 
molecules, by generating a phenomenon known as the Feshbach resonance, which 
causes two slowly colliding atoms to stick together into an unstable and 
short-lived compound.

This approach was used by a US team in 2003 to pair potassium atoms and create 
the world’s first ultracold diatomic molecules at about 150 nanokelvins above 
absolute zero.

In 2019, Zhao and his colleagues at USTC were using the method to produce 
two-atom molecules when they observed Feshbach resonances between atoms and 
molecules – instead of just atoms.

“Since then, we’ve been thinking about using them as components to build 
triple-atom molecules,” Zhao said. Finally, this year the researchers had 
indirect evidence that they had succeeded in forming triatomic structures.

But the molecules were short-lived and hard to confirm. For their latest study, 
the researchers switched to a different method, applying a fine-tuned magnetic 
field to help trigger Feshbach resonances between ultracold potassium-40 atoms 
and molecules made up of sodium-23 and potassium-40.

The results provided the first clear evidence of the production of ultracold 
three-atom molecules, their paper said.

“We explored different techniques to make this work, since we didn’t understand 
how the resonances work between atoms and molecules, and we didn’t even know 
how to theoretically describe such three-atom molecules,” Zhao said.

The team will now work to bring the weak and unstable molecules into a more 
stable state. Zhao said that in the longer term – once they have a better 
understanding and control of the process – they might take it a step further 
and try to make four-atom ultracold molecules.

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