Ultra-fast charging batteries that can be 70% recharged in just two minutes

Date: October 13, 2014
Source: Nanyang Technological University
http://www.sciencedaily.com/releases/2014/10/141013090449.htm

Scientists from Nanyang Technological University (NTU Singapore) have developed 
a new battery that can be recharged up to 70 per cent in only 2 minutes. The 
battery will also have a longer lifespan of over 20 years.

Expected to be the next big thing in battery technology, this breakthrough has 
a wide-ranging impact on many industries, especially for electric vehicles 
which are currently inhibited by long recharge times of over 4 hours and the 
limited lifespan of batteries.

This next generation of lithium-ion batteries will enable electric vehicles to 
charge 20 times faster than the current technology. With it, electric vehicles 
will also be able to do away with frequent battery replacements.

The new battery will be able to endure more than 10,000 charging cycles -- 20 
times more than the current 500 cycles of today's batteries.

NTU Singapore's scientists replaced the traditional graphite used for the anode 
(negative pole) in lithium-ion batteries with a new gel material made from 
titanium dioxide, an abundant, cheap and safe material found in soil. It is 
commonly used as a food additive or in sunscreen lotions to absorb harmful 
ultraviolet rays.

Naturally found in a spherical shape, NTU Singapore developed a simple method 
to turn titanium dioxide particles into tiny nanotubes that are a thousand 
times thinner than the diameter of a human hair.

This nanostructure is what helps to speeds up the chemical reactions taking 
place in the new battery, allowing for superfast charging.

Invented by Associate Professor Chen Xiaodong from the School of Materials 
Science and Engineering at NTU Singapore, the science behind the formation of 
the new titanium dioxide gel was published in the latest issue of Advanced 
Materials, a leading international scientific journal in materials science.

NTU professor Rachid Yazami, who was the co-inventor of the lithium-graphite 
anode 34 years ago that is used in most lithium-ion batteries today, said Prof 
Chen's invention is the next big leap in battery technology.

"While the cost of lithium-ion batteries has been significantly reduced and its 
performance improved since Sony commercialised it in 1991, the market is fast 
expanding towards new applications in electric mobility and energy storage," 
said Prof Yazami.

"There is still room for improvement and one such key area is the power density 
-- how much power can be stored in a certain amount of space -- which directly 
relates to the fast charge ability. Ideally, the charge time for batteries in 
electric vehicles should be less than 15 minutes, which Prof Chen's 
nanostructured anode has proven to do."

Prof Yazami, who is Prof Chen's colleague at NTU Singapore, is not part of this 
research project and is currently developing new types of batteries for 
electric vehicle applications at the Energy Research Institute at NTU (ERI@N).

Commercialisation of technology

Moving forward, Prof Chen's research team will be applying for a 
Proof-of-Concept grant to build a large-scale battery prototype. The patented 
technology has already attracted interest from the industry.

The technology is currently being licensed to a company and Prof Chen expects 
that the new generation of fast charging batteries will hit the market in two 
years' time. It holds a lot of potential in overcoming the longstanding power 
issues related to electro-mobility.

"With our nanotechnology, electric cars would be able to increase their range 
dramatically with just five minutes of charging, which is on par with the time 
needed to pump petrol for current cars," added Prof Chen.

"Equally important, we can now drastically cut down the waste generated by 
disposed batteries, since our batteries last ten times longer than the current 
generation of lithium-ion batteries."

The long-life of the new battery also means drivers save on the cost of a 
battery replacement, which could cost over USD$5,000 each.

Easy to manufacture

According to Frost & Sullivan, a leading growth-consulting firm, the global 
market of rechargeable lithium-ion batteries is projected to be worth US$23.4 
billion in 2016.

Lithium-ion batteries usually use additives to bind the electrodes to the 
anode, which affects the speed in which electrons and ions can transfer in and 
out of the batteries.

However, Prof Chen's new cross-linked titanium dioxide nanotube-based 
electrodes eliminate the need for these additives and can pack more energy into 
the same amount of space.

"Manufacturing this new nanotube gel is very easy," Prof Chen added. "Titanium 
dioxide and sodium hydroxide are mixed together and stirred under a certain 
temperature. Battery manufacturers will find it easy to integrate our new gel 
into their current production processes."

This battery research project took the team of four NTU Singapore scientists 
three years to complete and is funded by Singapore's National Research 
Foundation.

Last year, Prof Yazami was awarded the Draper Prize by the National Academy of 
Engineering for his ground breaking work in developing the lithium-ion battery 
with three other scientists.

Story Source:

The above story is based on materials provided by Nanyang Technological 
University. Note: Materials may be edited for content and length.

Journal Reference:

Yuxin Tang, Yanyan Zhang, Jiyang Deng, Jiaqi Wei, Hong Le Tam, Bevita 
Kallupalathinkal Chandran, Zhili Dong, Zhong Chen, Xiaodong Chen. Nanotubes: 
Mechanical Force-Driven Growth of Elongated Bending TiO2-based Nanotubular 
Materials for Ultrafast Rechargeable Lithium Ion Batteries (Adv. Mater. 
35/2014). Advanced Materials, 2014; 26 (35): 6046 DOI: 10.1002/adma.201470238

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Cheers,
Stephen                                           
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