Scientists Develop Liquid Fuel That Can Store The Sun's Energy For Up to 18 
Years

By Carly Cassella   November 06, 2018
https://www.sciencealert.com/scientists-develop-liquid-that-sucks-up-sun-s-energy/amp


No matter how abundant or renewable, solar power has a thorn in its side.

There is still no cheap and efficient long-term storage for the energy that it 
generates.

The solar industry has been snagged on this branch for a while, but in the past 
year alone, a series of papers has ushered in an intriguing new solution.

Scientists in Sweden have developed a specialised fluid, called a solar thermal 
fuel, that can store energy from the sun for well over a decade.

"A solar thermal fuel is like a rechargeable battery, but instead of 
electricity, you put sunlight in and get heat out, triggered on demand," 
Jeffrey Grossman, an engineer works with these materials at MIT explained to 
NBC News.

The fluid is actually a molecule in liquid form that scientists from Chalmers 
University of Technology, Sweden have been working on improving for over a year.

This molecule is composed of carbon, hydrogen and nitrogen, and when it is hit 
by sunlight, it does something unusual: the bonds between its atoms are 
rearranged and it turns into an energised new version of itself, called an 
isomer.

Like prey caught in a trap, energy from the sun is thus captured between the 
isomer's strong chemical bonds, and it stays there even when the molecule cools 
down to room temperature.

When the energy is needed - say at night-time, or during winter - the fluid is 
simply drawn through a catalyst that returns the molecule to its original form, 
releasing energy in the form of heat.

"The energy in this isomer can now be stored for up to 18 years," says one of 
the team, nanomaterials scientist Kasper Moth-Poulsen from Chalmers University.

"And when we come to extract the energy and use it, we get a warmth increase 
which is greater than we dared hope for."

A prototype of the energy system, placed on the roof of a university building, 
has put the new fluid to the test, and according to the researchers, the 
results have caught the attention of numerous investors.

The renewable, emissions-free energy device is made up of a concave reflector 
with a pipe in the centre, which tracks the Sun like a sort-of satellite dish.

The system works in a circular manner. Pumping through transparent tubes, the 
fluid is heated up by the sunlight, turning the molecule norbornadiene into its 
heat-trapping isomer, quadricyclane. The fluid is then stored at room 
temperature with minimal energy loss.

When the energy is needed, the fluid is filtered through a special catalyst 
that converts the molecules back to their original form, warming the liquid by 
63 degrees Celsius (113 degrees Fahrenheit).

The hope is that this warmth can be used for domestic heating systems, powering 
a building's water heater, dishwasher, clothes dryer and much more, before 
heading back to the roof once again.

The researchers have put the fluid through this cycle more than 125 times, 
picking up heat and dropping it off without significant damage to the molecule.

"We have made many crucial advances recently, and today we have an 
emissions-free energy system which works all year around," says Moth-Poulsen.

After a series of rapid developments, the researchers claim their fluid can now 
hold 250 watt-hours of energy per kilogram, which is double the energy capacity 
of Tesla's Powerwall batteries, according to the NBC.

But there's still plenty of room for improvement. With the right manipulations, 
the researchers think they can get even more heat out of this system, at least 
110 degrees Celsius (230 degrees Fahrenheit) more.

"There is a lot left to do. We have just got the system to work. Now we need to 
ensure everything is optimally designed," says Moth-Poulsen.

If all goes as planned, Moth-Poulsen thinks the technology could be available 
for commercial use within 10 years.

The most recent study in the series has been published in Energy & 
Environmental Science .

Cheers,
Stephen


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