Hello Brenton, I did some testing and found out the reason for the first error: 
It needs to the file type identified in LocalSettings.php with special 
configuration settings

You can find more info here:

https://www.mediawiki.org/wiki/Extension:Jmol#Managing_molecular_files

> Date: Wed, 4 Feb 2015 07:55:11 +1000
> From: [email protected]
> To: [email protected]
> Subject: [MediaWiki-l] Jmol errors
> 
> Hi,
> 
> I've installed the Jmol extension and I have noticed two major problems:
> 
> 1. When uploading a pdb file at Special:Upload I receive the error:
> 
> > File extension ".pdb" does not match the detected MIME type of the file
> > (text/plain).
> 
> Other chemical file extensions produce similar errors, including .sdf,
> .cml, etc. Even though I have added:
> 
> > $wgFileExtensions = array( 'doc', 'docx', 'xls', 'xlsx', 'mpp', 'pdf',
> > 'ppt', 'tiff', 'bmp', 'pptx', 'ps', 'odt', 'ods', 'odp', 'odg'
> > , 'ogg', 'sdf', 'mol', 'pdb', 'xyz', 'mol2', 'svg', 'cml'
> > );
> 
> to LocalSettings.php
> 
> 2. Whenever I add <jmolpdb></jmolpdb> to an article (any article, even my
> sandbox, i.e., User:Fuse809/sandbox), <jmolPdb></jmolPdb> or other Jmol
> tags <jmolFile></jmolFile> and click "Save page" I'm left at a blank page
> with the URL of
> http://localhost:8080/mediawiki/index.php?title=PAGENAME&action=submit
> (where PAGENAME is the page's name).
> 
> Thanks for your time,
> Brenton
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