Humm...
From the man page of userdel(8):
DESCRIPTION The userdel utility removes a user from the system, optionally removing that user's home directory and any subdirectories. So, it won't remove an user from a group, but an user from the entire system. No signs of removing from a group on the entire man page... Geez... seems like I won't find what I'm looking for... -- An OpenBSD user... and that's all you need to know =)