File a bug in bugzilla. Then attach an SMTP log to that bug by following 
  the steps at:

http://www.mozilla.org/quality/mailnews/mail-troubleshoot.html#imap

-Scott

Wayne Mery wrote:
> moz 0.9.9 build 2002041603
> 
> seeking wisdom...
> 
> When i address a message to a mail list defined in my address book, i 
> sometimes get
>   "An error occurred while sending mail.  The mail server has responded: 
> 5.6.0 Headers too large (32768 max)..."
> 
> This happens to all mail lists regardless of size. It has never happened 
> immediately after startup (I have to have been using moz for a while). 
> Restarting moz temporarily resolves the problem.
> 
> I didn't get a match in bugzilla.  I don't know what information to look 
> for or how to debug.  I don't know what triggers it, but it does not 
> appear to be related at all to the message contents.  I can't recreate 
> it at will, but once it starts, it happens on every attempted send if i 
> use a mail list from my address book.
> 
> ------------------------------------------------------------------------
> 


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