For those interested..

https://en.wikipedia.org/wiki/Tert-Butylthiol

Odo(u)r threshold is <0.33 parts per billion. 300 mL is probably enough for
an entire cities gas lines.... :) I used *a lot of bleach* to clean the
glass ware after that reaction.....LOL.

On Thu, May 28, 2020 at 1:03 PM Mac Doktor <[email protected]> wrote:

> On May 27, 2020, at 10:56 PM, alb.001 alb.001 <[email protected]>
> wrote:
>
> Talk about ammonia.   The thing I fear most when driving, especially on a
> highway is a tanker carrying anhydrous ammonia.  Several have crashed with
> resultant release of clear low-hanging clouds of ammonia gas.  If you drive
> thru one your lungs instinctively close and you suffocate while driving at
> speed.
>
> One night I was listening to the scanner and they started toning out every
> fire department and rescue squad for 30 miles around. The cooling system at
> a local poultry plant leaked and they have to evacuate over a hundred
> people. Eight had to be take to the hospital which used up three quarters
> of the ambulances in the area. The others were treating people on site.
> Fortunately there were no other major incidents for several hours and even
> then they had rescue squads from 30 minutes away filling quarters.
>
> I highly recommend the book *Hostile Waters*. It's about a Soviet nuclear
> missile sub that had a seawater leak into one of the missile tubes. There
> was a reaction with the solid rocket fuel that progressively filled the
> entire boat with nitric acid vapor. It's a harrowing story. You can't put
> the book down. It's on Amazon (buy a used copy):
>
> https://www.amazon.com/Hostile-Waters-Peter-Huchthausen/dp/0312169280
>
>
> They made a movie out of it. I haven't seen it but a friend told me it was
> crap compared to the book.
>
>
> On May 27, 2020, at 10:11 PM, Nicholas Stock <[email protected]> wrote:
>
>
> I distinctly remember the sweet smell of benzene (used as the solvent for
> the reaction).....that certainly wouldn't happen today....
>
>
> When I worked for a local printer the pressmen used copious amounts of
> something called "blanket wash". They poured the stuff onto lint-free rags
> and cleaned the printers with it. No gloves. I'm not sure but I think it
> was largely or entirely straight up benzene.
>
>
> As for smells, using 300 mL of tert-butyl mercaptan isn't for the feint of
> heart either....we had the fire-brigade called out a few times on that
> one...
>
>
> That's funny. I live next to a major highway and I occasionally get a
> whiff of something like that. Always seems to be after dark. I wonder what
> it could be?
>
> One of the guys on the Old Christmas Lights list told us that he used to
> chew the silvery tinsel they put on Xmas trees back in the Good Old Days.
> It was of course elemental lead. He said it had a very nice sweet taste.
>
> My freshman year in college we had a two hour lab once a week. I was
> appalled. No one knew how to pour from a reagent bottle or how to keep a
> scoop from being contaminated and the grad students running the lab didn't
> blink a lash. In High School our teacher spent three days on procedures and
> techniques like that.
>
>
> That summer chemistry class was a blast. I had nitric acid stains on my
> hands the rest of the year.
>
>
> Terry Bowman, KA4HJH
> "The Mac Doctor"
>
> “Reality is that which, when you stop believing in it, doesn't
> go away.”–Philip K. Dick, *I Hope I Shall Arrive Soon*
>
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