I tried the suggestion: 

> 1) untar the package, which should yield a directory xraylib-1.0.8
> 2) change the line "CC=gcc" in src/xraylib/src/makefile into
"CC=mingw32-gcc-4.4.0-dw2"
> 3) install the package from the directory into which you unzipped the
package as "pkg install xraylib-1.0.8"

The package seemed to compile with only warnings this time. However, I still
can't use any of the functions in the package. For example

octave-3.2.4.exe:18> AtomicWeight(4)
error: `AtomicWeight' undefined near line 18 column 1




For reference, here is the output when I installed the package. 
 
octave-3.2.4.exe:12> pkg install xraylib-1.0.8
xrayfiles.c:1: warning: -fPIC ignored for target (all code is position
independe
nt)
xrayglob.c:1: warning: -fPIC ignored for target (all code is position
independen
t)
xrayvars.c:1: warning: -fPIC ignored for target (all code is position
independen
t)
cross_sections.c:1: warning: -fPIC ignored for target (all code is position
inde
pendent)
scattering.c:1: warning: -fPIC ignored for target (all code is position
independ
ent)
atomicweight.c:1: warning: -fPIC ignored for target (all code is position
indepe
ndent)
edges.c:1: warning: -fPIC ignored for target (all code is position
independent)
fluor_lines.c:1: warning: -fPIC ignored for target (all code is position
indepen
dent)
fluor_yield.c:1: warning: -fPIC ignored for target (all code is position
indepen
dent)
jump.c:1: warning: -fPIC ignored for target (all code is position
independent)
coskron.c:1: warning: -fPIC ignored for target (all code is position
independent
)
radrate.c:1: warning: -fPIC ignored for target (all code is position
independent
)
cs_line.c:1: warning: -fPIC ignored for target (all code is position
independent
)
polarized.c:1: warning: -fPIC ignored for target (all code is position
independe
nt)
splint.c:1: warning: -fPIC ignored for target (all code is position
independent)

cs_barns.c:1: warning: -fPIC ignored for target (all code is position
independen
t)
rm: cannot lstat `libxrl.a': No such file or directory
make[1]: [external] Error 1 (ignored)
pr_data.c:1: warning: -fPIC ignored for target (all code is position
independent
)
xrayglob_inline.c:1: warning: -fPIC ignored for target (all code is position
ind
ependent)
xrayfiles_inline.c:1: warning: -fPIC ignored for target (all code is
position in
dependent)
warning: gen_doc_cache: unusable help text in 'xraylib'. Ignoring function.
warning: gen_doc_cache: unusable help text in 'xraylib'. Ignoring function.




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