Anyone already mentioned DocBook? 
(I am sorry if I mention it again if someone already did)
It is an Oasis-standard. Here a list of others who use it:
http://wiki.docbook.org/topic/WhoUsesDocBook

People can format the layout as they like in any file-format they like.

Eventually a standaard PDF can be created for people who do not need or
like to do extra work.

I write my documentation very often in DocBook, and OxygenXMLEditor
exports it to PDF

Some interesting reading: DocBook XSL: The Complete Guide, by Bob
Stayton: http://www.sagehill.net/docbookxsl/index.html

Bert


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