I'm joining the discussion late (I'm very busy these days). Lots of
good points were made before, and I also think that you are way over
thinking this and maybe you don't have the right tools. As I
understand you are using Linux, take a look at
http://www.darktable.org/ or http://rawtherapee.com/ and ... I really
don't like Gimp but can't suggest anything better.

Don't stress that much over sharpness, your eyes are the best "tools"
to pick a sharp image. Look at 100% magnification. If you want the
absolute best sharpness achievable after processing, get a copy of
"Real World Image Sharpening" by Bruce Faser. Gimp also has unsharp
mask and smart sharpening, probably not exactly the same as Photoshop,
but the idea behind the tools are the same.

With such a scene you have to decide if you are exposing for the
highlights or the shadows, or try HDR. Usually since this is a sunset
I'd expose for the sky and leave the rest as a silhouette like this:
http://500px.com/photo/43233840

Happy new year!

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