Here you go:
----- Original Message -----
From: Ann Sanfedele
Subject: Re: Help with terminology regarding B&W print wanted


> OUch - I can't even tell if you are kidding or not.  tarnish
makes
> silver black, why would
> it be called what makes black silver?   but you were kidding,
weren't
> you?


"
The shiny metallic deposits are caused by metallic silver on the
surface of
the paper. How it gets there is a more difficult process to
explain.

It is usually called mirroring out or silvering out. What
happens is
that over time imaging silver can begin to oxidize and break
down, when
this breakdown occurs silver ions break free from the silver
imaging
particles in the print. These silver ions are both invisible and
migratory and can actually move through the gelatin. This
movement
is halted when these ions run into a reducing agent (such as
sulfur)
and is reduced back to metallic silver (usually silver sulfide).

This occurs most often in the maximum density areas, simply
because
that is where the most silver is.

The reason that it appears on the surface of the print is that
that is the
most opportune location for these migrating silver ions to come
into
contact with reducing agents (sulfur in the atmosphere).

There is no known cure for this problem.

Roger Watson
Conservation Department
George Eastman House
900 East Avenue
Rochester, NY 14607
(716) 271-3361
"
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