Jerry,

 

There are many variables associated with zinc.  

 

One big one would be core duty and core inventory.  Higher duty cores
use sub-nucleate boiling.  The higher your core duty usually means the
high crud inventory and subsequent releases.  You are a 3-loop plant
which is very favorable as core duty is usually lower.  

 

During end of cycle deboration periods, the primary system water wants
to come to equilibrium so boron is released from the fuel.  This will
also release the cobalts, manganese, iron, etc and other isotopes with
the boron thus resulting with higher RCS activity.  When zinc is added
even more of these isotopes are released due to displacement. 

 

Since cyclic zinc is a player your strategy is important.  Typically
during the first few cycles of depleted zinc injection you add at a
reduced rate and only during the last few months of the cycle.  Since
that period is also the period the core releases crud in higher duty
cores you could see higher RCS than during previous outages.  Typically
first cycle is limited to 40-50 ppb months or 5 ppb for 8 months.
Higher numbers will cause higher releases during pre-outage periods.
Even after several cycles of zinc injection, if the injection rate is
increased at the end of cycle (say from 5 ppb to 8 ppb) you may see
another increase in RCS activity.  

 

So in effect the two mechanisms of release (deboration/core crud
inventory AND depleted zinc acetate injection rate/ppb months) can
results with elevated end of cycle dose rates.  Together these two items
can be down right nasty.    

 

Mitigation attention can be focused on the clean-up during the end of
cycle period.  

*       Fresh on-line Letdown bed put in 45 days prior to outage
(possible overlay of some type of specialty resin), 
*       Good (120 gpm) on-line letdown flow rates, 
*       Sub-micron CVCS filtration.  We prefer smaller sub-micron
filters but only if it results with minimal filter changes.  You don't
want to sacrifice letdown flowrates for filter changes so this needs
optimized. We prefer not more than 1 change per 2 week period but zero
is best.  
*       Increased EOC boron (20 ppm will see reduced core releases while
10 ppm will sum what stabilize releases) can help alleviate some of the
problems.  The Brits use 100 ppm EOC boron but US plants will not waste
the lost generation.  We have seen very good results at 50 ppm but it
would take a mid-cycle forced outage before nuclear fuels group will
permit such high EOC numbers.  The EOC boron will only effect pre-outage
and shutdown releases.  Forced oxidation will release that 2-5% not
released during the deboration period.  

 

Additional on-line dose rate monitoring:

*         We used our in plant dose rate instrumentation for ERO during
pre-outage

*         If we saw dose rate increases on area rad monitors (AR system)
we increased the RP dose rate base point survey periodicity in
accessible areas for CV / CS systems.  

*         I would also recommend increase chemistry sampling of RCS
during 10 weeks of pre-outage for early detection of potential increases
with RCS activity.  RCS activity increases will be seen before dose rate
increases are seen.    

 

Additional outage dose rate monitoring:

*         SI and RH systems will only see increases during shutdown
periods when RH is in use (e.g. reactor cool down and/or during forced
oxidation).  This means initial shutdown surveys may not see increased
dose rates in RH/SI until they are put into service.

*         If higher pre-outage dose rates are seen, during shutdown you
may want to pay attention to low flow areas of:

*         Pressurizer (RY), especially small bore lines or bypass lines
to spray valves 

*         Reactor Coolant (RC), especially loop crossovers, bypass, and
pressure equalization lines.  Dead legs such as the RC warm up lines may
also be affected.  

*         RCDT input and transfer to radwaste lines

*         Floor (RF) Drains (some RE lines tie into RF)

*         Equipment (RE) Drains 

*         Any other primary system drain piping such as S/G bowl drains.


 

Even if higher RCS pre-outage activity is experienced once forced
oxidation clean-up is completed elevated dose rates may be avoided.
Items like clean-up duration, flow rates, and resin strategy can help
avoid bad outages.

 

 

________________________________

From: [email protected] [mailto:[email protected]] On Behalf
Of Barber, Jerry
Sent: Saturday, March 02, 2013 2:34 PM
To: [email protected]
Subject: Powernet: Zn Injection - Initial Increases in Dose Rates

 

We are about to start injecting Zn at Robinson (finally!) which is a 3
loop Westinghouse PWR.  In addition to placing more ARMs at locations
along CVCS components and piping, we are also looking at any changes to
our routine surveillances that should be implemented.  For those plants
that still have folks around who can remember back when they first
started Zn injection:

 

*         Did you have any dose rate "surprises"?  If so, where?

*         Did you change the frequency of any routine radiological
surveillances?

 

Jerry Barber - RP Supervisor - Field Operations

Robinson Nuclear Plant

 

843-857-1496 Work

843-861-2524 Cell

[email protected]

 




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