The issue is that Gmail is forcing your From: address to be the same as 
your authenticated identity (to avoid spoofing).

You can add extra verified E-mail addresses to your Gmail account, and then 
you will be able to send using those as well.  It's in Gmail settings 
somewhere.

Beware that if the domain "org.com" is using SPF, then its SPF record in 
the DNS needs to allow outbound mail from Google's servers.  If org.com is 
already Google hosted that's fine - but then you'd be better logging into 
Google with an org.com GSuite account.

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