>But if you refine the full data with the same model, can there really be any 
>fundamental difference, if in one case you simply do a Fourier transform to real 
>space ?

Thanks to Stefan Bruehne for providing an obvious (in retrospect :-) answer i.e. that 
in Rietveld refinement we throw away the non-Bragg peak data, where-as with PDF all 
scattering is included. 

He quoted an example where PDF shows a split peak in Ga(1-x)In(x)As for Ga-As and 
In-As distances, where Rietveld refinement always gives the average (Ga,In)As 
structure.

Alan.

Alan Hewat, ILL Grenoble, FRANCE  <[EMAIL PROTECTED]> fax (33) 4.76.20.76.48
(33) 4.76.20.72.13 (.26 Mme Guillermet) http://www.ill.fr/dif/AlanHewat.htm 
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