Dear Rietvelders
I am trying to refine (fullprof) x-ray (Cu Ka) pattern of spinel CuTi2(S,Se)4 which was measured in flat specimen sample holder  in D8 Th:Th without monochromator (10-158 2Th). the experiment details were step each 0.02 2Th with 10 sec per step. the background was subtructed in EVA. 
the problem that i am facing is that the R_Bragg is 3.71 but the global chi2 is 7.5 only if i am excluded the region to 10 - 80 2Th. what can be the reason for that?
 
Thank's in advance for your ideas
 
Eli

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