>"Rietveld structure refinement of precipitated carbonate apatite using neutron 
>diffraction data".
>Wilson RM, Elliott JC, Dowker SE, Smith RI. (2004) Biomaterials. 25(11), 
>2205-13.

BTW, this paper is also in ICSD as is another neutron measurement that shows 
that silcate, like carbonate, substitues for phosphate; in this work the 
hydrogen atoms in the water are also located:

"The effect of the silicon incorporation on the hydroxylapatite structure. A 
neutron diffraction study".
Arcos, D.;Rodriguez-Carvajal, J.;Vallet-Regi, M. (2004) Solid State Sciences 6, 
987-994 

But you had better have some very good neutron data if you also have fluorine 
substituting for water as well as carbonate for phosphate :-)

_____________________________________________________________
Dr Alan Hewat, ILL Grenoble, FRANCE<[EMAIL PROTECTED]>fax+33.476.20.76.48
+33.476.20.72.13 (.26 Mme Guillermet)  http://www.ill.fr/dif/people/hewat/
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