If you can fit via a sum of a broader lorentzian and a narrower one it may indicate the sample is a "mixture". Are you sure the sample is microscopically homogenous?

Best,

Jon




Francois Goutenoire schrieb:
Dear Rietveld users,

I am currently working on Williamson-Hall graph in order to check strain effect on some new phase.

I have some hyper-lorentzian peaks eta>1 from a pseudo-Voigt decomposition , then I am not able to get BetaL and BetaG from Winplotr decomposition.

Does anyone have an idea ?


Francois Goutenoire
Laboratoire des Oxydes et des Fluorures, UMR6010.




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