In my experience, there are two sources of "gunk" on wheels.  One, as posited 
in this thread is the oxidation of the metal track (and wheels!), while the 
other has nothing to do with the track, but instead with plastic wheels.  If 
you were to take a sample of the gunk on the wheels, not that on the track, I 
think you would find a curious mix of compounds.  To be sure, nickel or brass 
oxide would be there, and may be the actual binder that holds it all together, 
but there would be other elements too, derived from the dust from various 
sources.  This dust comes from human skin (the most common source of house 
dust!) as well as all those materials and processes we use to make our layouts. 
 Plaster dust (short lived until it meets di-hydrogen monoxide), sawdust, 
plastic dust (from that kitbash project) etc, etc.  These microscopic dust 
particles are attracted to electrostatic charges.  The key here is static.  
Active electricity does not attract this dust, but static electricity does.  
Since metal wheels on metal track are all conductive, there is no static charge 
developed here.  Plastic wheels, however, can develop a static charge, albeit 
small, that is enough to pick up those micron dust particles from the roadbed 
and place them at the point of highest charge, the contact point of plastic to 
metal.  To be sure, when running a mix of metal and plastic wheeled cars, the 
majority of gunk develops on the plastic wheels first, then apparently migrates 
to the metal wheels.

I believe this to be true, although I don't have the government grant and 
ensuing research to prove it.  On a previous club layout, we started with a mix 
of metal and plastic wheels.  Dirt (track gunk) was a constant problem.  
Cleaning was required once a month if there was any significant operation.  The 
club then mandated that all equipment operated on the layout must have metal 
wheels.  Plastic wheels were verboten!  Tadaaa!  Dirt on wheels and track was 
practically eliminated!  Occasionally someone would sneak in to the layout and 
run their plastic wheeled cars.  We always knew.  The track suddenly needed 
cleaning for no apparent reason.

Now, I agree, and believe that the oxidation of nickel from the rail (and 
wheels) may be a major source of that specific form of gunk, I believe that 
plastic wheels bring in a whole new dynamic.

Darrell Smith

--- In [email protected], "johnalbee03@..." <johnalbee03@...> wrote:
>
> Fascinating.  When I ran my finger down a new stick of flex, I got "black".   
> Oxidation?
> You're saying, if I understand it, the metal wheels contacting the track,  
> cause arcing (sp) which pits the track?
> Then, please "splain" why ya get gunk with plastic wheels.  Really curious,  
> thanks
> 




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