Re: [biofuels-biz] The Hydrogen hype, the scam artists at work.

2003-07-11 Thread Michael Allen

Murdoch,

There have been several ideas put forward over the years to indicate that 
if space is composed of anything, it is rarefied hydrogen and maybe 
helium. Deep space is basically, (I am told), made up of hydrogen atoms at 
a variable density but typically individual molecules at about 100 mm (4) 
apart. There was a proposal to make a deep-space vehicle propelled on the 
ram-jet principle to scoop these up, heat them in a fusion reactor and 
chuck them out the back. I'm pretty sure NASA published details of the 
proposal some 20 years ago.

It also seems generally agreed that the sun, like other stars, keeps going 
by fission of hydrogen to helium (and higher elements too). Because of its 
large gravity, hydrogen from the space around the sun would be attracted to 
the sun. As it happens, both hydrogen and helium have thermal molecular 
velocities above the escape velocity of Earth but not (I am told) of 
Jupiter, Saturn and perhaps Neptune. Perhaps there are puddles of the stuff 
out there at the bottom of a very serious gravity-well.

But I do know from personal experience that keeping hydrogen confined on 
Planet Earth is bloody difficult and quite dangerous!

Incidentally, re your 1 in 10, has any professional scientist or engineer 
at any of the US space agencies ever gone on record to say hydrogen *does 
not* leave our atmosphere in the general direction of up?

Regards

Michael Allen
Thailand


 Interesting responses, thx.

 On Tue, 08 Jul 2003 15:19:53 +0700, you wrote:

 Sorry Murdoch,

 Didn't realise you had some questions in here.

 I forget what the escape velocity is for Planet Earth. But I know that 
 normal hydrogen molecules exceed it. That is why free hydrogen does not 
 exist in our planet's atmosphere. Like free water on the moon, it just 
 keeps going.

 But you have a point: I would imagine that some hydrogen reacts with 
 oxygen and ozone along the way. And perhaps with nitrogen too if the 
 circumstances are right. I can't give you details because upper 
 atmospheric chemistry and physics is above and beyond me :-.

 Actually, over the years, I have been on the side of trying to claim that 
 some
 significant amounts of Hydrogen may escape Earth's atmosphere when 
 chemically
 liberated, but I have usually been met with skepticism at best, shouting- 
 down by
 professional scientists at worst.  Your agreeing with the overall idea 
 of this
 is maybe a 1 in 5 or 10 type of response.


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Re: [biofuels-biz] The Hydrogen hype, the scam artists at work.

2003-07-11 Thread murdoch

Incidentally, re your 1 in 10, has any professional scientist or engineer 
at any of the US space agencies ever gone on record to say hydrogen *does 
not* leave our atmosphere in the general direction of up?

Regards

Michael Allen
Thailand

Not that I can think of.  

I haven't spoken with them directly (to my knowledge sometimes they are
around but don't id themselves) though I did call a UCSD researcher once, just
to try to give myself some better background on H2 in general.  He was answering
my questions from out of the blue and kept emphasizing the danger of H2
handling.  He felt that, in and of itself, this reason probably precluded an H2
economy.  He was not responsive to my concerns about atmospheric hydrogen
depletion, nor is anyone else usually.  But that was just one researcher
(Chemistry I think, but with some aspect of Earth Science) answering questions
from out of the blue.

There was one knowledgeable person on the biofuel discussion board who was not
outright dismissive once I explained what I was getting at.  More often than
not, folks assume that since they conceive of H2 as reacting with anything at
all times, that no H2 could possible leave the atmosphere because it will react
with something before it leaves.  Sometimes this view is mitigated.  

My own concern is that, if we liberate globally massive amounts of Hydrogen in
processes that were heretofore not going on, then we might see net
Earth-System-Mass-depletion and H2 depletion.  While this seems like an offbeat
concern, I've just been keeping my eye open to see if there's any validity to
it.  I first heard the question raised on an NPR show about H2, a couple of
years ago.  The person who raised it turns out to have been right on the money
as to Hydrogen escaping its confinement, regularly, and I wonder if they were
right in their depletion concerns.

It's hard to ask about when it's usually dismissed out of hand without decent
reasoning.  Also, they often say that H2 is added to the Earth every day so
what's the big deal? or something like that.  But no, I haven't taken anything
to NASA.

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Re: [biofuels-biz] The Hydrogen hype, the scam artists at work.

2003-07-10 Thread murdoch

Interesting responses, thx.

On Tue, 08 Jul 2003 15:19:53 +0700, you wrote:

Sorry Murdoch,

Didn't realise you had some questions in here.

I forget what the escape velocity is for Planet Earth. But I know that 
normal hydrogen molecules exceed it. That is why free hydrogen does not 
exist in our planet's atmosphere. Like free water on the moon, it just 
keeps going.

But you have a point: I would imagine that some hydrogen reacts with oxygen 
and ozone along the way. And perhaps with nitrogen too if the circumstances 
are right. I can't give you details because upper atmospheric chemistry and 
physics is above and beyond me :-.

Actually, over the years, I have been on the side of trying to claim that some
significant amounts of Hydrogen may escape Earth's atmosphere when chemically
liberated, but I have usually been met with skepticism at best, shouting-down by
professional scientists at worst.  Your agreeing with the overall idea of this
is maybe a 1 in 5 or 10 type of response.


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Re: [biofuels-biz] The Hydrogen hype, the scam artists at work.

2003-07-08 Thread Michael Allen

Sorry Murdoch,

Didn't realise you had some questions in here.

I forget what the escape velocity is for Planet Earth. But I know that 
normal hydrogen molecules exceed it. That is why free hydrogen does not 
exist in our planet's atmosphere. Like free water on the moon, it just 
keeps going.

But you have a point: I would imagine that some hydrogen reacts with oxygen 
and ozone along the way. And perhaps with nitrogen too if the circumstances 
are right. I can't give you details because upper atmospheric chemistry and 
physics is above and beyond me :-.

Hydrogen embrittlement is encountered in the process of making methanol 
from natural gas and several other processes where hydrogen forms. It is 
generally thought to be due to the reaction of hydrogen with iron carbides 
in the steel forming methane under huge pressures. Chromium carbides are 
much more stable so equipment for handling hydrogen as a hot gas is usually 
made out of high chromium steels (Hastelloy C for example). Austenitic 
stainless steel cannot be used because welding reduces the local chromium 
content. I think that work-hardening also becomes serious below about -20C 
for both austenitic S/S and all the Hastelloys. The best bet is probably 
some thick-walled magnesium-aluminium alloy with piping fabricated in 304 
S/S. Why not ask NASA?

Of course these materials cost more than common low carbon steels. 
Technically it may be possible to put hydrogen under very high pressures 
and very low temperature into road tankers and coastal vessels for 
transportation. It may even be possible to put a tank in every automobile 
in the world. But it will not IMO be a low cost solution. And in true 
Hollywood style, there is a much greater risk of a car exploding on impact 
if it is storing very high pressure hydrogen in a fuel tank within it 
somewhere.

Sorry about the delay

Michael Allen
Thailand
   On Fri, 04 Jul 2003 23:10:37 -0700, murdoch [EMAIL PROTECTED] 
wrote:

 On Mon, 30 Jun 2003 10:44:52 +0700, you wrote:

 Dear Hakan,

 Your summary of hydrogen production technology is, IMO, spot on.

 However you say nothing about the distribution losses that have always 
 plagued City Gas (which also contains carbon monoxide). This is not, 
 as is commonly supposed, just caused by poorly maintained pipes: The 
 hydrogen molecule is so very small that it can pass through atomic sized 
 gaps. As a consequence, some pretty sophisticated equipment is required 
 for its compression, storage and distribution. Even stainless steel 
 pipes can lose hydrogen molecules! When I was working with the stuff, I 
 was warned of the severe explosion risk caused by hydrogen lines, 
 particularly in ducts, due to its very wide flammability range and its 
 ability to find the smallest hole to escape through. I also remember 
 that I was on no account to put my finger over a leaking hydrogen jet 
 because the small molecule would pass through my skin and cause an 
 embolism. In fact the only advantage of hydrogen storage and 
 transportation that I ever discovered was that it doesn't hang around 
 when it leaks: It heads straight up and tries to leave this planet.

 Question is: how much of it succeeds?

 For this reason, hydrogen carrying pipes were/are always brought around 
 the outside of buildings. It is true that NASA has made some truly 
 remarkable advances in the safe handling of hydrogen. But somehow I 
 can't see my local filling station being able to match NASA even though 
 they have considerable experience in handling compressed natural gas 
 (CNG) and liquid propane gas (LPG) as transport fuels. Hydrogen is in an 
 entirely different league. And then, of course, there is hydrogen 
 embrittlement  . .

 What is hydrogen embrittlement?




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Re: [biofuels-biz] The Hydrogen hype, the scam artists at work.

2003-07-05 Thread murdoch

On Mon, 30 Jun 2003 10:44:52 +0700, you wrote:

Dear Hakan,

Your summary of hydrogen production technology is, IMO, spot on.

However you say nothing about the distribution losses that have always 
plagued City Gas (which also contains carbon monoxide). This is not, as 
is commonly supposed, just caused by poorly maintained pipes: The hydrogen 
molecule is so very small that it can pass through atomic sized gaps. As a 
consequence, some pretty sophisticated equipment is required for its 
compression, storage and distribution. Even stainless steel pipes can lose 
hydrogen molecules! When I was working with the stuff, I was warned of the 
severe explosion risk caused by hydrogen lines, particularly in ducts, due 
to its very wide flammability range and its ability to find the smallest 
hole to escape through. I also remember that I was on no account to put my 
finger over a leaking hydrogen jet because the small molecule would pass 
through my skin and cause an embolism. In fact the only advantage of 
hydrogen storage and transportation that I ever discovered was that it 
doesn't hang around when it leaks: It heads straight up and tries to leave 
this planet. 

Question is: how much of it succeeds?

For this reason, hydrogen carrying pipes were/are always 
brought around the outside of buildings. It is true that NASA has made some 
truly remarkable advances in the safe handling of hydrogen. But somehow I 
can't see my local filling station being able to match NASA even though 
they have considerable experience in handling compressed natural gas (CNG) 
and liquid propane gas (LPG) as transport fuels. Hydrogen is in an entirely 
different league. And then, of course, there is hydrogen embrittlement  . . 

What is hydrogen embrittlement?



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Re: [biofuels-biz] The Hydrogen hype, the scam artists at work.

2003-06-29 Thread Michael Allen

Dear Hakan,

Your summary of hydrogen production technology is, IMO, spot on.

However you say nothing about the distribution losses that have always 
plagued City Gas (which also contains carbon monoxide). This is not, as 
is commonly supposed, just caused by poorly maintained pipes: The hydrogen 
molecule is so very small that it can pass through atomic sized gaps. As a 
consequence, some pretty sophisticated equipment is required for its 
compression, storage and distribution. Even stainless steel pipes can lose 
hydrogen molecules! When I was working with the stuff, I was warned of the 
severe explosion risk caused by hydrogen lines, particularly in ducts, due 
to its very wide flammability range and its ability to find the smallest 
hole to escape through. I also remember that I was on no account to put my 
finger over a leaking hydrogen jet because the small molecule would pass 
through my skin and cause an embolism. In fact the only advantage of 
hydrogen storage and transportation that I ever discovered was that it 
doesn't hang around when it leaks: It heads straight up and tries to leave 
this planet. For this reason, hydrogen carrying pipes were/are always 
brought around the outside of buildings. It is true that NASA has made some 
truly remarkable advances in the safe handling of hydrogen. But somehow I 
can't see my local filling station being able to match NASA even though 
they have considerable experience in handling compressed natural gas (CNG) 
and liquid propane gas (LPG) as transport fuels. Hydrogen is in an entirely 
different league. And then, of course, there is hydrogen embrittlement  . . 
. . . .


Regards

Michael Allen

On Wed, 25 Jun 2003 07:09:01 +0200, Hakan [EMAIL PROTECTED] wrote:


 Here is some more thought provoking parts in my article the scam artists 
 at work

 The Hydrogen hype, the scam artists at work.

 As mentioned, it is around 80 years old technologies and have been used 
 in submarine technologies for a long time. It is often talked about as 
 the energy solution for the future. The most common source of hydrogen 
 (City gas), is gasification of coal and it has been used as City gas for 
 a century. It can be produced by electrolysis of water, but the 
 electricity needed is very close to the energy gained. If the electricity 
 is produced by hydrogen also, it becomes negative. The future value of 
 hydrogen is not really as an energy resource, when not produced from 
 fossil fuels, but more as a conversion and energy storage method. Only in 
 a situation of large coal reserves and/or large electricity surplus 
 production, hydrogen would be valuable as fuel. In short term the large 
 electricity production could come from nuclear and other traditional 
 sources and on very long term Solar and Wind production could come into 
 play.

 Hydrogen is like the fairy tales. To make 10 kW of Hydrogen from 
 renewable source like electrolysis of water, you need 9 kW of 
 electricity. Where is that electricity coming from? You do not need much 
 knowledge to see that it is not enough hydrogen in this process, to 
 produce more Hydrogen. To produce electricity from Hydrogen in fuel cells 
 it is 30 to 50% efficiency, the same as a NG or diesel electricity 
 plants. So if you put your 10 kW of Hydrogen in a fuel cell, you have 3 
 to 5 kW to use. Where did the original 9 kW come from? I think that the 
 scam artists at work have some basic (nucleus) plans for this.

 Hydrogen was very much in use 50 years ago and is still common in the 
 former Soviet Union. It is called City Gas and produced from 
 gasification of coal. The major known reserves of coal are in US, Russia 
 and EU. The use of coal have gone down and with the current use of coal, 
 the known reserves will last around 200 years (R/P value). For US the R/P 
 value is 235 years, but in a Hydrogen economy the R/P values will rapidly 
 go down to double digits. It is a worrying attitude, sold by the scam 
 artists at work. They want you to believe that coal is a salvation, even 
 if the usage goes up 3-4 times and that US still would have coal for 235 
 years. It might come as a surprise for many, but it does not work that 
 way. The more you use of a finite resource, the faster it will be 
 finished. For me it is logical, how about you?

 Hakan



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Re: [biofuels-biz] The Hydrogen hype, the scam artists at work.

2003-06-25 Thread David Teal

Hakan,
Your perspective on hydrogen is probably right and needs saying in public.
You make comparisons with gas from coal.  I remember in the days before
methane was discovered in the North Sea (known as 'North Sea' gas rather
than 'Natural' gas here in Britain by the way), and most towns  cities had
their gasworks sited near the railway, canal or navigable river bringing in
the coal.  In Britain, the Commonwealth and elsewhere the product was known
as 'Towns gas' rather than 'City gas'.  The carbon monoxide content made it
more toxic than methane.  Apart from the points you made, these old gasworks
are among the most polluted sites in the land, with naptha, phenols, tars 
sulphur compounds still in the soil, long after the bad egg smells have gone
away.  The same would apply to gas from biomass (or turkey guts), though
with modern pollution abatement methods I suppose it can be kept under
control.
An interesting side note was that tar from the gasworks was used to surface
roads at bus stops because it does not soften in the oil dripping from bus
engines.
At a meeting a couple of years ago, a delegate suggested that the best
policy for global warming would be to burn all the world's trapped methane
before it escaped into the atmosphere.  Then there is the issue of methane
hydrate on the sea bed..

Dvid T.


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