RE: [Vo]:SRI Case Expt 4He

2010-02-25 Thread Jones Beene
From: Steven Krivit 

 

http://newenergytimes.com/v2/news/2010/SRI-Case-Repl/SRI-Case.shtml 

Has anybody ever noticed that 2 out of 3 runs that show 4He growth in the
SRI Case replication show a peak and then a decrease in 4He?

This is a helium leak-tight chamber.

Where does the 4He go?

 

Two explanations come to mind.

1)There is no such thing as leak proof for helium - in the ppb range,
and that is why it is called leak-tight. A few ppb per week would be
expected.

2)The measurement itself removes the missing helium which otherwise
would be flat.




 



Re: [Vo]:SRI Case Expt 4He

2010-02-25 Thread Horace Heffner


On Feb 24, 2010, at 7:37 PM, Steven Krivit wrote:


http://newenergytimes.com/v2/news/2010/SRI-Case-Repl/SRI-Case.shtml

Has anybody ever noticed that 2 out of 3 runs that show 4He growth  
in the SRI Case replication show a peak and then a decrease in 4He?


This is a helium leak-tight chamber.

Where does the 4He go?

s


The helium flows out of the cell with the evolved H2 and O2 gasses.   
If helium production slows and cell gas production remains constant  
then the concentration of helium in the gas produced diminishes.   
Modeling this over time is not so simple in the real case, as it is a  
multi-compartment flow model,  and one in which one of the flow  
compartments (the Pd) performs in an unpredictable manner.


To answer your question more directly, the helium continually flows  
out of the cell with the effluent, which is sampled periodically.  If  
helium production stops, then the helium concentration necessarily  
must eventually drop to zero because the cell gas is continually  
produced and water is periodically added to the electrolyte to  
continue operation.


Best regards,

Horace Heffner
http://www.mtaonline.net/~hheffner/






Re: [Vo]:SRI Case Expt 4He

2010-02-25 Thread Jed Rothwell

Steven Krivit wrote:


http://newenergytimes.com/v2/news/2010/SRI-Case-Repl/SRI-Case.shtml

Has anybody ever noticed that 2 out of 3 runs that show 4He growth 
in the SRI Case replication show a peak and then a decrease in 4He?


Yes. Many people have noted this. At ICCF-15 Tom Passell distributed 
a paper about this, which McKubre and Storms disagreed with. As I 
recall he said the helium was there all along and it was freed up and 
then sequestered again.




This is a helium leak-tight chamber.


Nothing is perfectly leak-tight, and helium is the most difficult 
element to contain, according to Morrison. The steel cylinders used 
by Miles contained the stuff for months with remarkably little 
leaking, but they were less complicated than a working cell. For Run 
SC4.2, they drew 9 samples. Anything you can draw a sample out of 9 
times is bound to leak.




Where does the 4He go?


I do not know. I think that is unclear to the researchers. I think it 
is either sequestered or leaked. I do not think it is lost to the 
sampling technique, per Jones Beene, but I could be wrong about that. 
Since the concentration is above atmosphere (5 ppm), any leaks would 
be out, not in.


No doubt there is some freeing up followed by sequestering going on 
here, as you see from SC1, in which the helium level fluctuates 
slightly below 1 ppm. It can't be leaking out, since this is so far 
below atmospheric concentration. It can only leak in.


This is the first question regarding helium that you have raised that 
is not answered, or at least addressed to my satisfaction, in the literature.


- Jed



Re: [Vo]:SRI Case Expt 4He

2010-02-25 Thread Jed Rothwell

Horace Heffner wrote:

Has anybody ever noticed that 2 out of 3 runs that show 4He growth 
in the SRI Case replication show a peak and then a decrease in 4He?


. . .


The helium flows out of the cell with the evolved H2 and O2 gasses.


Nope. This is the Case cell: D2 gas loaded, no evolved gas.

This is done with a direct, on-line, high-resolution mass 
spectrometric measurement  of [4He]. I figure something like that 
has gotta leak. I mean, it must leak more than a simple collection 
flask that you send off to the Bureau of Mines. Those tubes running 
up to a mass spectrometer with Swarlok connections can't be as 
air-tight as a flask.


The last experiment shown in this paper is the Arata 
double-structured cathode. That's really a gas loading experiment, 
not electrolysis. From the perspective of a helium study it is more 
like gas loading. The helium should be trapped inside the double 
structure walls. The latest Arata experiments are gas loading no 
matter how you look at them.


This paper covers a lot of ground in 9 pages.

- Jed



Re: [Vo]:SRI Case Expt 4He

2010-02-25 Thread Horace Heffner


On Feb 24, 2010, at 7:37 PM, Steven Krivit wrote:


http://newenergytimes.com/v2/news/2010/SRI-Case-Repl/SRI-Case.shtml

Has anybody ever noticed that 2 out of 3 runs that show 4He growth  
in the SRI Case replication show a peak and then a decrease in 4He?


This is a helium leak-tight chamber.

Where does the 4He go?

s


Oooops!  I didn't notice the subject was on the Case experiment.


Best regards,

Horace Heffner
http://www.mtaonline.net/~hheffner/