Re: orion-list Radiocarbon datings

2001-11-10 Thread Barbara Leger

I'm just curious after reading the message below, what would be
considered kosher in the preparation of the scrolls and what
would not be, and if that would help this discussion.

Just a thought,
Barb Leger

David C. Hindley wrote:

 Geoff Hudson asks:

 Is there any possibility that 'old' carbon was in the food chain of
 animals reared in the Dead Sea area, and whose skins were used for the
 Scrolls?

 From, perhaps, the eating pitch or asphalt that had risen to the
 surface of the Dead Sea? I've never heard of sheep or goats doing
 this, but it is a distinct possibility.

 In the past I have been amazed at the kind of things reindeer eat on
 occasion (amanita muscaria mushrooms and urine tainted snow), so
 eating pitch, etc., is not impossible. However, I do know that
 ingestion of even small amounts of distilled petroleum products,
 including naphthalene, can be deadly, so I wonder if this could have
 occurred to any great degree.

 Another possibility might be petroleum products (naphthalene?) that
 were used in the preparation of parchment. The medieval process using
 quicklime to remove the hair and soften the hide was known from about
 the 4th century, I understand, but it is not certain what was done
 prior to this, especially to soften the skins. The process of hide
 tanning used by native American Indians included using oil (although
 it was an oil of animal origin) to soften the skin, along with salt to
 dehair it.

 Respectfully,

 Dave Hindley
 Cleveland, Ohio, USA


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RE: orion-list Radiocarbon datings

2001-11-10 Thread Geoff Hudson

Is there any possibility that 'old' carbon was in the food chain of animals
reared in the Dead Sea area, and whose skins were used for the Scrolls?
Geoff Hudson

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RE: orion-list Radiocarbon datings

2001-11-10 Thread David C. Hindley

Geoff Hudson asks:

Is there any possibility that 'old' carbon was in the food chain of
animals reared in the Dead Sea area, and whose skins were used for the
Scrolls?

From, perhaps, the eating pitch or asphalt that had risen to the
surface of the Dead Sea? I've never heard of sheep or goats doing
this, but it is a distinct possibility.

In the past I have been amazed at the kind of things reindeer eat on
occasion (amanita muscaria mushrooms and urine tainted snow), so
eating pitch, etc., is not impossible. However, I do know that
ingestion of even small amounts of distilled petroleum products,
including naphthalene, can be deadly, so I wonder if this could have
occurred to any great degree.

Another possibility might be petroleum products (naphthalene?) that
were used in the preparation of parchment. The medieval process using
quicklime to remove the hair and soften the hide was known from about
the 4th century, I understand, but it is not certain what was done
prior to this, especially to soften the skins. The process of hide
tanning used by native American Indians included using oil (although
it was an oil of animal origin) to soften the skin, along with salt to
dehair it.

Respectfully,

Dave Hindley
Cleveland, Ohio, USA


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RE: orion-list Radiocarbon datings

2001-11-10 Thread Suter, David

Having been involved in raising goats for show, I find it extremely unlikely
that such animals would have ingested pitch or asphalt.  Goats browse, but
on wood products, including tree bark, leaves of shrubs, grass, etc.

David Suter
Saint Martin's College 

-Original Message-
From: David C. Hindley
To: [EMAIL PROTECTED]
Sent: 11/10/01 8:31 AM
Subject: RE: orion-list Radiocarbon datings

Geoff Hudson asks:

Is there any possibility that 'old' carbon was in the food chain of
animals reared in the Dead Sea area, and whose skins were used for the
Scrolls?

From, perhaps, the eating pitch or asphalt that had risen to the
surface of the Dead Sea? I've never heard of sheep or goats doing
this, but it is a distinct possibility.

In the past I have been amazed at the kind of things reindeer eat on
occasion (amanita muscaria mushrooms and urine tainted snow), so
eating pitch, etc., is not impossible. However, I do know that
ingestion of even small amounts of distilled petroleum products,
including naphthalene, can be deadly, so I wonder if this could have
occurred to any great degree.

Another possibility might be petroleum products (naphthalene?) that
were used in the preparation of parchment. The medieval process using
quicklime to remove the hair and soften the hide was known from about
the 4th century, I understand, but it is not certain what was done
prior to this, especially to soften the skins. The process of hide
tanning used by native American Indians included using oil (although
it was an oil of animal origin) to soften the skin, along with salt to
dehair it.

Respectfully,

Dave Hindley
Cleveland, Ohio, USA
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Re: orion-list Radiocarbon datings and DNA

2001-10-31 Thread RLWinnetka

Greg Doudna [EMAIL PROTECTED] wrote:

 Marco Rotman wrote on Oct. 22, 2001:
 
  Having followed the discussion so far, it seems to me that Radiocarbon
  datings are useless for dating DSS-fragments (esp. when coming from cave
 4)
  due to the fact that it is unknown if (and if so, how much) castor oil is
  used on the fragment.
  1) Is this conclusion correct?
  2) Would DNA-research lead to more reliable conclusions regarding the date
  of a given manuscript? Or are there similar problems here?
 
 
 What exists now falls a little short of the objective of reliable
 14C datings for individual Qumran texts. Yet this statement
 requires qualification and explanation. In all likelihood most
 of the existing 14C datings on Qumran texts are accurate as
 reported. The problem is that right now it is what I liken to a
 Russian roulette situation--there may be a few dates affected
 by contamination among the 19 Qumran texts dated in the
 Zurich and Tucson series, and our problem is we don't
 know for sure which, or how many.
 
 'Useless' is too strong, however. First, it may be that most
 of the existing datings will be checked and verified at some
 point as having been done on uncontaminated samples, and
 thus the existing datings which are accurate can be distinguished
 from the existing datings for which there may be known
 problems. (rest of useful discussion snipped for brevity)

Greg, since the castor oil was used to enhance the readability of _inscriptions_, it 
seems unlikely to me that the problem is as severe as postulated in the worst case 
study.  Surely the specimens used for destructive carbon 14 testing were taken from 
blank margins, not the actual inscriptions.  Of course, if the specimen were 
thoroughly saturated, the oil could have migrated to the margins also--but probably at 
much lower concentrations.

Robert D. Leonard Jr.
Winnetka, Illinois
U.S.A.
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Re: orion-list Radiocarbon datings of Qumran texts

2001-10-19 Thread A. J. T. Jull



Dear Greg,

I agree improved methods are always desirable.  However, you should caution
the reader as follows:

1. You set up a straw man that castor oil is a problem, perhaps it is.
2. the tests done in Copenhagen were done on medieval parchments and not
any DSS samples, and
3. the castor-oil effect was studied for the maximum contamination (perhaps
excessively...?) - a small amount used in the '50s might have little
effect.
4. the conclusion that the pretreatment could not have removed all of the
oil first of all assumes that the samples were all treated with castor
oil, and that this treatment affected the age.  There is no proof this is
the case, although I agree one cannot exclude it completely.
5. the fact that most of the samples gave the expected age tends to argue
against the entire argument - do you propose all of the samples are 300 yr
too young and the oldest DSS are really 400-450 BC?

I would also note that the paper of Jull et al discusses treatments with
acetone.   One could easily do addition studies with more complex solvent
extractions (as I believe Rasmussen et al recommend).

Tim Jull
University of Arizona

Greg Doudna wrote:


 Conclusion:
 'Our experiments demonstrate that the AAA-treatment used in
 the Zurich and Arizona 14C series could not have removed all
 oil, whether fossil or modern, possibly introduced into the
 DSS fragments.
 'Lest the implications for Scroll studies be overlooked, this
 conclusion implies that the two series of 14C datings of the DSS
 that have been conducted up to the present (Bonani et al. 1992
 and Jull et al. 1995) cannot be guaranteed to have removed all
 of the modern carbon present in any samples if they had been
 contaminated with castor oil and hence could have produced
 some 14C dates that were younger than the texts' true ages.
 'It is therefore necessary to devise a revised procedure capable
 of removing all castor oil in order to enable individual Qumran
 text 14C datings to be relied upon with confidence. It remains
 to be seen whether a similar conclusion applies to DSS samples
 that have been treated with British Museum Leather Dressing.'
 end conclusion

 (Comment [not in the published article]: In the body of the
 article, the data based on testing of medieval parchment samples
 intentionally contaminated
 and then cleaned and dated, compared to identical control
 samples uncontaminated and dated, show the maximum possible
 effect of castor oil contamination on a Qumran fragment--if totally
 saturated--would be c. 300 years erroneously young. The actual
 extent of contamination--in cases where this was a factor--much
 more likely be only a fraction of total saturation, and after the AAA
 cleaning done by Zurich and Tucson, would give dates erroneously
 offset toward modern by much less than 300 years. Since the
 extent of castor oil contamination in any given case cannot be
 known, there is no means to calculate a specific offset, apart from the
 calculated upper limit that will not exceed 300 years error. It
 must be emphasized that there is at present neither evidence that
 castor oil was present on any of the Qumran text samples that
 were dated, nor evidence that castor oil was not present on any
 of the Qumran text samples that were dated. All we know is that
 there was use of castor oil on fragments in the Rockefeller
 Museum in the early days and, in light of the data reported here,
 we have a problem that needs solving.--GD)

 Greg Doudna


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