Re: [Biofuel] Worst WVO Ever?

2008-05-31 Thread Thomas Kelly
Al,
 I spent a few hours monkeying around with this stuff. I succeeded in 
making soap.

A couple of years ago I split the glyc. mix  methanol recovery. I 
blended the FFAs that split out with BD to fuel my oil-fired heating 
system. I can't help but think that somebody dumped FFAs into the dumpster. 
A sample from the top titrated 19; deeper titrated 24!!!  The FFAs split 
from the glyc mix titrate 33. Maybe they split the glyc in order to recover 
the methanol, and had no use for the FFAs.

 The good news:  This stuff burns nicely in a friend's waste oil heater. 
A 100+ gal will help heat his shop next winter.
   Thanks for the good advice,
  Tom



- Original Message - 
From: A. Lawrence [EMAIL PROTECTED]
To: sustainablelorgbiofuel@sustainablelists.org
Sent: Friday, May 30, 2008 7:59 PM
Subject: Re: [Biofuel] Worst WVO Ever?


 
  My thoughts as well  ...  after sleeping on it. I have a cubie
 (4.5gal/17.7L) of the WVO. As time permits I'll do some test batches 
 using
 A/B two step. As the price of veg oil increases, some restaurants are
 changing less frequently. It might be a good idea for me to become better
 acquainted with processing bad oil. If I can convert this stuff I can
 probably deal with just about anything.

  Since you are an experienced A/B two stepper, I'd like your thoughts
 on
 the following:
  I have had great success composting glycerin after it has been split
 from the mix.
 Unsplit glycerin composts, but does not seem to do as well as split glyc.
 I
 suspect the presence of soaps is the reason.
  A/B two step not only increases yield, but should reduce the amount
 of
 soap produced  .  Yes?   - once neutralized, the glyc from A/B
 two
 step more closely resembles the split glyc.

   Best to You,

 Tom

 Hi Tom,  All I do with my glycerine is mix it with sawdust and burn it.
 Indeed, I get less glycerine from using the 2-step method, but beyond 
 that,
 I don't monkey with it... Not to appear terse, (I can't remember the exact
 science) but as memory serves, the 2-step allows more oil to be made into
 bio-fuel, hence, less glycerine... I'd ask you to have a peek at the JTF
 site, again, not to appear terse - I'll be revisiting too, to refresh my
 memory. (D'oh!) Single step is well-suited to gently used oil, but 
 hard-used
 oil demands 2-step, unless you'd like a 30% (or so)return of oil and 70%
 glyc... If there's Magnesol in it - run for your life!! It's a BDr's
 nightmare!!

 Regards, Al

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Re: [Biofuel] Worst WVO Ever?

2008-05-31 Thread A. Lawrence
Hi Tom,

Using it to heat a shop or such is probably the best thing you can do with
something as haywire as that - glad you found out *before* you made a large
batch of soap... I still have a lot of that bad oil from the supplier I
let go, and will continue to work with it, but it's sure nasty stuff...
monetarily - not worth the effort... environmentally - gotta do it... as for
the advice, my favorite one-liner; Take my advice - I'm not using it...
g




 Al,
  I spent a few hours monkeying around with this stuff. I succeeded in
 making soap.

 A couple of years ago I split the glyc. mix  methanol recovery. I
 blended the FFAs that split out with BD to fuel my oil-fired heating
 system. I can't help but think that somebody dumped FFAs into the
dumpster.
 A sample from the top titrated 19; deeper titrated 24!!!  The FFAs split
 from the glyc mix titrate 33. Maybe they split the glyc in order to
recover
 the methanol, and had no use for the FFAs.

  The good news:  This stuff burns nicely in a friend's waste oil
heater.
 A 100+ gal will help heat his shop next winter.
Thanks for the good advice,
   Tom




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Re: [Biofuel] Worst WVO Ever?

2008-05-30 Thread A. Lawrence

  My thoughts as well  ...  after sleeping on it. I have a cubie
 (4.5gal/17.7L) of the WVO. As time permits I'll do some test batches using
 A/B two step. As the price of veg oil increases, some restaurants are
 changing less frequently. It might be a good idea for me to become better
 acquainted with processing bad oil. If I can convert this stuff I can
 probably deal with just about anything.

  Since you are an experienced A/B two stepper, I'd like your thoughts
on
 the following:
  I have had great success composting glycerin after it has been split
 from the mix.
 Unsplit glycerin composts, but does not seem to do as well as split glyc.
I
 suspect the presence of soaps is the reason.
  A/B two step not only increases yield, but should reduce the amount
of
 soap produced  .  Yes?   - once neutralized, the glyc from A/B
two
 step more closely resembles the split glyc.

   Best to You,

Tom

Hi Tom,  All I do with my glycerine is mix it with sawdust and burn it.
Indeed, I get less glycerine from using the 2-step method, but beyond that,
I don't monkey with it... Not to appear terse, (I can't remember the exact
science) but as memory serves, the 2-step allows more oil to be made into
bio-fuel, hence, less glycerine... I'd ask you to have a peek at the JTF
site, again, not to appear terse - I'll be revisiting too, to refresh my
memory. (D'oh!) Single step is well-suited to gently used oil, but hard-used
oil demands 2-step, unless you'd like a 30% (or so)return of oil and 70%
glyc... If there's Magnesol in it - run for your life!! It's a BDr's
nightmare!!

Regards, Al

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Re: [Biofuel] Worst WVO Ever?

2008-05-29 Thread Thomas Kelly
Thanks Al,

Best advice I'd offer is pass on this on please unless you've
 got plenty of time, patience, resources, and methods of dealing with the
 consequences... and they aren't pleasant...

 My thoughts as well  ...  after sleeping on it. I have a cubie 
(4.5gal/17.7L) of the WVO. As time permits I'll do some test batches using 
A/B two step. As the price of veg oil increases, some restaurants are 
changing less frequently. It might be a good idea for me to become better 
acquainted with processing bad oil. If I can convert this stuff I can 
probably deal with just about anything.

 Since you are an experienced A/B two stepper, I'd like your thoughts on 
the following:
 I have had great success composting glycerin after it has been split 
from the mix.
Unsplit glycerin composts, but does not seem to do as well as split glyc. I 
suspect the presence of soaps is the reason.
 A/B two step not only increases yield, but should reduce the amount of 
soap produced  .  Yes?   - once neutralized, the glyc from A/B two 
step more closely resembles the split glyc.

  Best to You,
  Tom
- Original Message - 
From: A. Lawrence [EMAIL PROTECTED]
To: sustainablelorgbiofuel@sustainablelists.org
Sent: Wednesday, May 28, 2008 8:46 PM
Subject: Re: [Biofuel] Worst WVO Ever?





 Al,
  BTW, I have other suppliers with very dark oil and their stuff
 titrates and
 processes as it should...

  Me too. Looks can be deceiving, huh?
 
 Tom

 Tom,  Looks can sure be that... that Magnesol (if that's what is going on)
 is an absolute nightmare to deal with... I have been doing the A/B two 
 step
 for a long time now, and it works much better than I could ever imagine a
 single stage process doing (further on in this thread). However, the 
 results
 are still all over the map - if I use the methoxide mix titration calls 
 for,
 *usually* it's instantly more soap than fuel, so cutting back on the
 methoxide helps, but even at that, the variance between batches from the
 same supplier won't allow me to use experience to tweak it to the right
 place. Incremental changes up or down even slightly seem somehow to be
 magnified... Best advice I'd offer is pass on this on please unless 
 you've
 got plenty of time, patience, resources, and methods of dealing with the
 consequences... and they aren't pleasant... Al


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[Biofuel] Worst WVO Ever?

2008-05-28 Thread Thomas Kelly
Hi All,
 I was offered a dumpster full of WVO. New owner of a diner inherited it 
from the previous owner. I tested a sample  . clean, fairly light in color 
.  titrated 19g KOH/L !!!
 (My previous high was 11 g KOH/L, but that oil was very dark.)

 The label on the dumpster says that the kitchen grease will be returned 
to the food chain as a component of animal feed. I would just as soon keep it 
out of the food chain and make 100+ gal of biodiesel. Will the two stage 
acid/base method handle such WVO as this? Am I looking for trouble pumping out, 
and getting stuck with, 100+ gal of burnt-out oil?

 The new owner is willing to give me his WVO which is nothing like what's 
in the dumpster.
Advice appreciated,
  Tom
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Re: [Biofuel] Worst WVO Ever?

2008-05-28 Thread Roger
I'd cut it with some better oil, but I've never tried any that bad either.


Thomas Kelly wrote:
 Hi All,
  I was offered a dumpster full of WVO. New owner of a diner inherited 
 it from the previous owner. I tested a sample  . clean, fairly light in 
 color .  titrated 19g KOH/L !!!
  (My previous high was 11 g KOH/L, but that oil was very dark.)

  The label on the dumpster says that the kitchen grease will be 
 returned to the food chain as a component of animal feed. I would just as 
 soon keep it out of the food chain and make 100+ gal of biodiesel. Will the 
 two stage acid/base method handle such WVO as this? Am I looking for trouble 
 pumping out, and getting stuck with, 100+ gal of burnt-out oil?

  The new owner is willing to give me his WVO which is nothing like what's 
 in the dumpster.
 Advice appreciated,
   Tom
 -- next part --
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Re: [Biofuel] Worst WVO Ever?

2008-05-28 Thread A. Lawrence

I recently dumped a WVO supplier because their oil has become
unmanageable - my best guess is that they are using Magnesol to filter it,
and get more mileage out of it... The titration was all over the spectrum,
and yes, for those of you that would ask, all was well with the titration
chemicals, and process... Test batches done at titration levels varied in
result, and again, I suspected I had a bad component somewhere, but even
with many test batches, only changing one component at a time to control the
outcome(s), it was never anywhere near what the titration said it should
be... Titration results suddenly went up with the change of ownership...
hmmm..
So, that's my best guess, and my exp. with that sort of thing... and BTW, I
have other suppliers with very dark oil and their stuff titrates and
processes as it should... good luck with that, Al

FWIW, I don't eat there either... :-|




 Hi All,
  I was offered a dumpster full of WVO. New owner of a diner inherited
it from the previous owner. I tested a sample  . clean, fairly light in
color .  titrated 19g KOH/L !!!
  (My previous high was 11 g KOH/L, but that oil was very dark.)

  The label on the dumpster says that the kitchen grease will be
returned to the food chain as a component of animal feed. I would just as
soon keep it out of the food chain and make 100+ gal of biodiesel. Will the
two stage acid/base method handle such WVO as this? Am I looking for trouble
pumping out, and getting stuck with, 100+ gal of burnt-out oil?

  The new owner is willing to give me his WVO which is nothing like
what's in the dumpster.
 Advice appreciated,
   Tom
 Biofuel mailing list
 Biofuel@sustainablelists.org
 http://sustainablelists.org/mailman/listinfo/sustainablelorgbiofuel

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Re: [Biofuel] Worst WVO Ever?

2008-05-28 Thread Mike Pelly
Try a liter batch in a blender and see what you get. Good luck with it. Mike


-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] On Behalf Of
Thomas Kelly
Sent: Wednesday, May 28, 2008 11:16 AM
To: biofuel
Subject: [Biofuel] Worst WVO Ever?

Hi All,
 I was offered a dumpster full of WVO. New owner of a diner inherited
it from the previous owner. I tested a sample  . clean, fairly light in
color .  titrated 19g KOH/L !!!
 (My previous high was 11 g KOH/L, but that oil was very dark.)

 The label on the dumpster says that the kitchen grease will be
returned to the food chain as a component of animal feed. I would just as
soon keep it out of the food chain and make 100+ gal of biodiesel. Will the
two stage acid/base method handle such WVO as this? Am I looking for trouble
pumping out, and getting stuck with, 100+ gal of burnt-out oil?

 The new owner is willing to give me his WVO which is nothing like
what's in the dumpster.
Advice appreciated,
  Tom
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Re: [Biofuel] Worst WVO Ever?

2008-05-28 Thread Thomas Kelly
Al,
 BTW, I have other suppliers with very dark oil and their stuff 
titrates and
processes as it should...

 Me too. Looks can be deceiving, huh?
   Tom
- Original Message - 
From: A. Lawrence [EMAIL PROTECTED]
To: sustainablelorgbiofuel@sustainablelists.org
Sent: Wednesday, May 28, 2008 3:12 PM
Subject: Re: [Biofuel] Worst WVO Ever?



 I recently dumped a WVO supplier because their oil has become
 unmanageable - my best guess is that they are using Magnesol to filter 
 it,
 and get more mileage out of it... The titration was all over the spectrum,
 and yes, for those of you that would ask, all was well with the titration
 chemicals, and process... Test batches done at titration levels varied in
 result, and again, I suspected I had a bad component somewhere, but even
 with many test batches, only changing one component at a time to control 
 the
 outcome(s), it was never anywhere near what the titration said it should
 be... Titration results suddenly went up with the change of ownership...
 hmmm..
 So, that's my best guess, and my exp. with that sort of thing... and BTW, 
 I
 have other suppliers with very dark oil and their stuff titrates and
 processes as it should... good luck with that, Al

 FWIW, I don't eat there either... :-|




 Hi All,
  I was offered a dumpster full of WVO. New owner of a diner 
 inherited
 it from the previous owner. I tested a sample  . clean, fairly light 
 in
 color .  titrated 19g KOH/L !!!
  (My previous high was 11 g KOH/L, but that oil was very dark.)

  The label on the dumpster says that the kitchen grease will be
 returned to the food chain as a component of animal feed. I would just 
 as
 soon keep it out of the food chain and make 100+ gal of biodiesel. Will 
 the
 two stage acid/base method handle such WVO as this? Am I looking for 
 trouble
 pumping out, and getting stuck with, 100+ gal of burnt-out oil?

  The new owner is willing to give me his WVO which is nothing like
 what's in the dumpster.
 Advice appreciated,
   Tom
 Biofuel mailing list
 Biofuel@sustainablelists.org
 http://sustainablelists.org/mailman/listinfo/sustainablelorgbiofuel

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 http://journeytoforever.org/biofuel.html

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 messages):
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Re: [Biofuel] Worst WVO Ever?

2008-05-28 Thread Thomas Kelly
Roger,
I'd cut it with some better oil, ..

It would take a hell of a lot of cutting   .  like  10:1.  Hate to ruin 
good oil.
I'm thinking about running a test batch using 2 step acid/base.
   Tom
- Original Message - 
From: Roger [EMAIL PROTECTED]
To: sustainablelorgbiofuel@sustainablelists.org
Sent: Wednesday, May 28, 2008 5:49 PM
Subject: Re: [Biofuel] Worst WVO Ever?


 I'd cut it with some better oil, but I've never tried any that bad either.


 Thomas Kelly wrote:
 Hi All,
  I was offered a dumpster full of WVO. New owner of a diner 
 inherited it from the previous owner. I tested a sample  . clean, 
 fairly light in color .  titrated 19g KOH/L !!!
  (My previous high was 11 g KOH/L, but that oil was very dark.)

  The label on the dumpster says that the kitchen grease will be 
 returned to the food chain as a component of animal feed. I would just 
 as soon keep it out of the food chain and make 100+ gal of biodiesel. 
 Will the two stage acid/base method handle such WVO as this? Am I looking 
 for trouble pumping out, and getting stuck with, 100+ gal of burnt-out 
 oil?

  The new owner is willing to give me his WVO which is nothing like 
 what's in the dumpster.
 Advice appreciated,
   Tom
 -- next part --
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Re: [Biofuel] Worst WVO Ever?

2008-05-28 Thread Thomas Kelly
Mike,
 Try a liter batch in a blender and see what you get. Good luck with it. 
 Mike

 Do you mean a liter batch using single stage base, or a liter batch 
using 2 stage acid/base?
  Tom
- Original Message - 
From: Mike Pelly [EMAIL PROTECTED]
To: sustainablelorgbiofuel@sustainablelists.org
Sent: Wednesday, May 28, 2008 6:33 PM
Subject: Re: [Biofuel] Worst WVO Ever?


 Try a liter batch in a blender and see what you get. Good luck with it. 
 Mike


 -Original Message-
 From: [EMAIL PROTECTED]
 [mailto:[EMAIL PROTECTED] On Behalf Of
 Thomas Kelly
 Sent: Wednesday, May 28, 2008 11:16 AM
 To: biofuel
 Subject: [Biofuel] Worst WVO Ever?

 Hi All,
 I was offered a dumpster full of WVO. New owner of a diner inherited
 it from the previous owner. I tested a sample  . clean, fairly light 
 in
 color .  titrated 19g KOH/L !!!
 (My previous high was 11 g KOH/L, but that oil was very dark.)

 The label on the dumpster says that the kitchen grease will be
 returned to the food chain as a component of animal feed. I would just 
 as
 soon keep it out of the food chain and make 100+ gal of biodiesel. Will 
 the
 two stage acid/base method handle such WVO as this? Am I looking for 
 trouble
 pumping out, and getting stuck with, 100+ gal of burnt-out oil?

 The new owner is willing to give me his WVO which is nothing like
 what's in the dumpster.
Advice appreciated,
  Tom
 -- next part --
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Re: [Biofuel] Worst WVO Ever?

2008-05-28 Thread A. Lawrence



 Al,
  BTW, I have other suppliers with very dark oil and their stuff
 titrates and
 processes as it should...

  Me too. Looks can be deceiving, huh?
Tom

Tom,  Looks can sure be that... that Magnesol (if that's what is going on)
is an absolute nightmare to deal with... I have been doing the A/B two step
for a long time now, and it works much better than I could ever imagine a
single stage process doing (further on in this thread). However, the results
are still all over the map - if I use the methoxide mix titration calls for,
*usually* it's instantly more soap than fuel, so cutting back on the
methoxide helps, but even at that, the variance between batches from the
same supplier won't allow me to use experience to tweak it to the right
place. Incremental changes up or down even slightly seem somehow to be
magnified... Best advice I'd offer is pass on this on please unless you've
got plenty of time, patience, resources, and methods of dealing with the
consequences... and they aren't pleasant... Al


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