I believe it seems to be just the fact that the solution conducts
electricity that counts .. that it is an electrolyte.    Any more
knowledgeable member can correct me if it seems "obviously wrong".

Oily black deposit??  Oily implies (usually) a covalent substance (though
not always).  The reaction of rust removal seems awfully ionic.   Could you
repeat again .. where exactly the oily stuff forms ... and as a result of
WHAT ... that it forms??

A water solution of Sodium Chloride ... electrolysed ... bubbles hydrogen
gas at the negative terminal .... chlorine at the positive ... just like
hydrogen fuel generation.   The Sodium of the Sodium Chloride .. combines
with the -OH radical of the water ... and forms a solution of Sodium
Hydroxide (Lye).  A background reaction that also takes place is that some
of the Chlorine ... bubbling through the resulting sodium hydroxide .. forms
sodium hypochlorite (clorox).

The hydrogen .... "burned" in an atmosphere of chlorine .. forms hydrogen
chloride ... which is QUICKLY absorbed by water ... forming a solution of
HYDROCHLORIC ACID.

Hope that helps.   Sorry to take so long to reply to this thread.

Curtis

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----- Original Message -----
From: Keith Addison <[EMAIL PROTECTED]>

So maybe it's the sodium that counts. Did you try plain salt?

With washing soda, do you also get the oily black deposit, and do you know
what it is?

Dunno if you remember this, on making NaOH from table salt.
http://cator.hsc.edu/~kmd/caveman/projects/chloralkali/slideshow/index.html

You end up with hydrogen and chlorine, which I guess you could turn into
hydrochloric acid, not sure quite how though (nor how to concentrate it
after that). Anyone have any ideas on that?

You'd end up with more table salt - sodium chloride instead of sodium
phosphate - which you could turn into more NaOH. Does that make any sense?
This might help close the loop, and phosphoric is expensive.

Traditionally soapstock is acidulated with strong sulphuric acid, but since
phosphoric works just as well HCl should be okay, though I'm not sure about
safety considerations.



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