Re: [Vo]:diversity, one of the 6 pillars of LENR
What you say is absolutely true, Bob. I don't believe that LENR occurred in the MFMP Bang! experiment. However the conditions were very similar to the Lugano experiment at that temperature and with the fuel that MFMP used. Check the Lugano SEM images of their Ni ash and compare to the SEM images of the MFMP Ni ash. The images are almost identical. What I am saying is that the conditions for LENR were likely pretty close to the same. We would love to test some Parkhomov ash from an experiment that has shown notable (outside error bar) excess heat. If we don't see that from Parkhomov, hopefully we will see it reported from someone else among the many replicators of Parkhomov. Since we are unlikely to get any ash from Rossi's HotCat, it is incumbent on the replicators to do long runs and have isotopic analysis done on their fuel and their ash. On Tue, Mar 3, 2015 at 10:59 PM, Bob Cook frobertc...@hotmail.com wrote: Axil and Bob-- You both seem to ignore the statement from the Lugano experiment that the Ni isotopic concentrations changed during the reaction. It would be nice to get an isotopic analysis of the MFMP and the Parkhomov experiment's Ni powder available after the experiment to see if there are changes from normal Ni. I am not sure either the Parkhomov nor the MFMP test have good evidence of a nuclear reaction with a change in nuclear species or total mass of the the system. Without an evident mass-to-energy conversion, what is the source of the explosive energy release in the two experiments? I do not consider either experiment has sufficient time producing XH to be indicative of LENR. That is not to say the two experimental set-ups have no potential for producing excess heat, if properly controlled. ( I would agree that there seemed to be a start of an excess heat reaction prior to the bangs, however the extent of this production of excess heat was not very long. ) Bob - Original Message - *From:* Bob Higgins rj.bob.higg...@gmail.com *To:* vortex-l@eskimo.com *Sent:* Tuesday, March 03, 2015 9:23 PM *Subject:* Re: [Vo]:diversity, one of the 6 pillars of LENR See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous
Re: [Vo]:diversity, one of the 6 pillars of LENR
This is not true. There are many physical and chemical thing happening that set the stage for LENR, and just because the stage has been set, it doesn't mean the show started. The chemical changes are the dissociation of the LiAlH4 and the dissolving of the Ni (at higher temperatures). The physical changes include the low temperature sintering of the cleaned Ni into a 3D web. Hydrogen cleaning of the Ni and the alumina surfaces allowed the molten metal to wet which is a chemical reaction in a sense because it involves monatomic hydrogen attachment to the surface oxide in the case of the alumina and stripping of the oxide to water vapor in the case of the Ni. Lots going on before LENR occurs. On Tue, Mar 3, 2015 at 11:17 PM, Axil Axil janap...@gmail.com wrote: This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. Thanks for your first hand observation. Doesn't your observation mean that the MFMP BANG was a LENR event since the fuel residue between Lagano and the bang are affected in the same way? Without the bang, the fuel is unchanged. I believe that I had seen that fuel difference reported on facebook or ECat news.
Re: [Vo]:diversity, one of the 6 pillars of LENR
This is a wonderful video, so thanks for pointing us to watch it. However, the molten Li-Al is not in a super-critical phase, but as he said, it doesn't have to be supercritical - just hot and high pressure. He also demonstrated a chemical mixing that produced nanoparticles as a precipitate. That kind of chemical mixing is not taking place in the Parkhomov/Rossi reactor as near as I am able to identify. That having been said, and as I posted before, the Li-Al-Ni-H alloy becomes saturated with Ni. It may be possible to cycle the temperature (up to dissolve and down to precipitate) and get the Ni to precipitate on the surface of the remaining solid Ni like a co-deposition - taking H- anions with it into the Ni surface at an accelerated rate. Dennis Cravens pointed me to a very interesting paper that has many similarities to this process: http://lenr-canr.org/acrobat/LiawBYelevatedte.pdf See the paper by Liaw. On Tue, Mar 3, 2015 at 10:57 PM, Axil Axil janap...@gmail.com wrote: There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. https://www.youtube.com/watch?v=6zurHSq4CB4 This video shows how a super critical medium produces nanoparticles from dissolved ionic substances when there is a super critical phase transition caused by cooling the super critical medium so that the dissolved solids nucleate and form nanoparticles. Both dissolved Lithium, aluminum, and hydrides will nucleate and form nanoparticle in a cooled region of the supercritical hydrogen gas.
Re: [Vo]:diversity, one of the 6 pillars of LENR
One of the things not sampled in the Lugano experiment is the product gas or gas ash. This may have very important clues to the nature of the reaction. In my replication (under construction), I intend to be able to collect the product gas for analysis off-site. We could find enhanced deuterium, tritium, and helium as a result of the process. The HotCat was not outfitted to be able to collect this gas - when they opened it, they just had to let it go woosh into the air. On Tue, Mar 3, 2015 at 11:07 PM, Axil Axil janap...@gmail.com wrote: I believe that the reactor would need to run for some time like it did at Lagano for nuclear changes to show up. Maybe the Russian experiment that produced XP ran long enough to show changes. On Wed, Mar 4, 2015 at 12:59 AM, Bob Cook frobertc...@hotmail.com wrote: Axil and Bob-- You both seem to ignore the statement from the Lugano experiment that the Ni isotopic concentrations changed during the reaction. It would be nice to get an isotopic analysis of the MFMP and the Parkhomov experiment's Ni powder available after the experiment to see if there are changes from normal Ni. I am not sure either the Parkhomov nor the MFMP test have good evidence of a nuclear reaction with a change in nuclear species or total mass of the the system. Without an evident mass-to-energy conversion, what is the source of the explosive energy release in the two experiments? I do not consider either experiment has sufficient time producing XH to be indicative of LENR. That is not to say the two experimental set-ups have no potential for producing excess heat, if properly controlled. ( I would agree that there seemed to be a start of an excess heat reaction prior to the bangs, however the extent of this production of excess heat was not very long. ) Bob
[Vo]:diversity, one of the 6 pillars of LENR
Dear Friends, Daily News focused on the Hot Cat, Axil's explanation and a few thoughts about unity or diversity in LENR-.all here: http://egooutpeters.blogspot.ro/2015/03/seeking-truth-and-power-of-lenr.html New replications at the horizon. Murphy, you never sleep? Peter -- Dr. Peter Gluck Cluj, Romania http://egooutpeters.blogspot.com
Re: [Vo]:diversity, one of the 6 pillars of LENR
Peter-- Your EGO-OUT report by Axil-Dixit sounds like it was written by Axil Axil who reports frequently on Vortex-l. Axil-Dixit's comments about the non-participating role of Ni in the Ni reaction is NOT borne out by the change of isotopic concentration measured in the Lugano Hot Cat test. Bob Cook - Original Message - From: Peter Gluck To: Arik El Boher ; Bo Hoistadt ; Brian Ahern ; CMNS ; Dagmar Kuhn ; doug marker ; Dr. Braun Tibor ; eCatNews ; Gabriel Moagar-Poladian ; Gary ; Haiko Lietz ; jeff aries ; Lewan Mats ; Nicolaie N. Vlad ; Peter Mobberley ; Pierre Clauzon ; Roberto Germano ; Roy Virgilio ; Sunwon Park ; vlad ; VORTEX ; Mark Tsirlin ; Steve Katinski ; David Daggett ; Valerio Ciampoli ; Peter Bjorkbom ; Peter Schlosser Sent: Tuesday, March 03, 2015 9:55 AM Subject: [Vo]:diversity, one of the 6 pillars of LENR Dear Friends, Daily News focused on the Hot Cat, Axil's explanation and a few thoughts about unity or diversity in LENR-.all here: http://egooutpeters.blogspot.ro/2015/03/seeking-truth-and-power-of-lenr.html New replications at the horizon. Murphy, you never sleep? Peter -- Dr. Peter Gluck Cluj, Romania http://egooutpeters.blogspot.com
Re: [Vo]:diversity, one of the 6 pillars of LENR
Dear Bob, Axil is my friend and collaborator. This AXIL DIXIT- axil says' is his column in Ego Out. Peter On Tue, Mar 3, 2015 at 8:26 PM, Bob Cook frobertc...@hotmail.com wrote: Peter-- Your EGO-OUT report by Axil-Dixit sounds like it was written by Axil Axil who reports frequently on Vortex-l. Axil-Dixit's comments about the non-participating role of Ni in the Ni reaction is *NOT* borne out by the change of isotopic concentration measured in the Lugano Hot Cat test. Bob Cook - Original Message - *From:* Peter Gluck peter.gl...@gmail.com *To:* Arik El Boher elboh...@missouri.edu ; Bo Hoistadt bo.hois...@physics.uu.se ; Brian Ahern ahern_br...@msn.com ; CMNS c...@googlegroups.com ; Dagmar Kuhn dagmar.k...@gmx.de ; doug marker dsmar...@gmail.com ; Dr. Braun Tibor br...@mail.iif.hu ; eCatNews p...@ecatnews.com ; Gabriel Moagar-Poladian gamo...@yahoo.com ; Gary g...@garywright.com ; Haiko Lietz h...@haikolietz.de ; jeff aries arias...@aol.com ; Lewan Mats mats.le...@nyteknik.se ; Nicolaie N. Vlad nicolaienv...@gmail.com ; Peter Mobberley petermobber...@hotmail.com ; Pierre Clauzon pierre.clau...@orange.fr ; Roberto Germano germ...@promete.it ; Roy Virgilio r.virgi...@gmail.com ; Sunwon Park swp...@kaist.ac.kr ; vlad v...@zpenergy.com ; VORTEX vortex-l@eskimo.com ; Mark Tsirlin tsirlin.m...@hotmail.com ; Steve Katinski steve...@aol.com ; David Daggett david.l.dagg...@gmail.com ; Valerio Ciampoli v.ciamp...@gmail.com ; Peter Bjorkbom peter.bjork...@neofire.com ; Peter Schlosser schloss...@t-online.de *Sent:* Tuesday, March 03, 2015 9:55 AM *Subject:* [Vo]:diversity, one of the 6 pillars of LENR Dear Friends, Daily News focused on the Hot Cat, Axil's explanation and a few thoughts about unity or diversity in LENR-.all here: http://egooutpeters.blogspot.ro/2015/03/seeking-truth-and-power-of-lenr.html New replications at the horizon. Murphy, you never sleep? Peter -- Dr. Peter Gluck Cluj, Romania http://egooutpeters.blogspot.com -- Dr. Peter Gluck Cluj, Romania http://egooutpeters.blogspot.com
Re: [Vo]:diversity, one of the 6 pillars of LENR
Axil-- I may be mixing golden delicious and red delicious apples, but I do not think I have mixed up oranges with respect to either the Lugano test or Parknomov's test. You may not recognize an apple when you see one(: Both the tests in question use an alumina container, nickel...as a fuel, add heat via electrical circuits etc. As far as I know, they may both have used Li as well as a catalyst or fuel. The reaction temperature seems to be in the same ballpark for both tests. And hydrogen seems to be involved in each test. How do you think the two experiments differ in significant design aspects that are documented? Maybe I would agree with you, if I understand the differences you perceive based on reported facts from the respective tests. For example, do you know of changes or lack thereof in the Ni isotope concentrations resulting from Parkhomov's test? Bob Cook - Original Message - From: Axil Axil To: vortex-l Sent: Tuesday, March 03, 2015 1:43 PM Subject: Re: [Vo]:diversity, one of the 6 pillars of LENR Bob, Your mixing apples and oranges. The Lagano test has nothing to do with the latest Dr. Parkhomov's experiment of the 27th/28th February. On Tue, Mar 3, 2015 at 1:26 PM, Bob Cook frobertc...@hotmail.com wrote: Peter-- Your EGO-OUT report by Axil-Dixit sounds like it was written by Axil Axil who reports frequently on Vortex-l. Axil-Dixit's comments about the non-participating role of Ni in the Ni reaction is NOT borne out by the change of isotopic concentration measured in the Lugano Hot Cat test. Bob Cook - Original Message - From: Peter Gluck To: Arik El Boher ; Bo Hoistadt ; Brian Ahern ; CMNS ; Dagmar Kuhn ; doug marker ; Dr. Braun Tibor ; eCatNews ; Gabriel Moagar-Poladian ; Gary ; Haiko Lietz ; jeff aries ; Lewan Mats ; Nicolaie N. Vlad ; Peter Mobberley ; Pierre Clauzon ; Roberto Germano ; Roy Virgilio ; Sunwon Park ; vlad ; VORTEX ; Mark Tsirlin ; Steve Katinski ; David Daggett ; Valerio Ciampoli ; Peter Bjorkbom ; Peter Schlosser Sent: Tuesday, March 03, 2015 9:55 AM Subject: [Vo]:diversity, one of the 6 pillars of LENR Dear Friends, Daily News focused on the Hot Cat, Axil's explanation and a few thoughts about unity or diversity in LENR-.all here: http://egooutpeters.blogspot.ro/2015/03/seeking-truth-and-power-of-lenr.html New replications at the horizon. Murphy, you never sleep? Peter -- Dr. Peter Gluck Cluj, Romania http://egooutpeters.blogspot.com
Re: [Vo]:diversity, one of the 6 pillars of LENR
Bob, Your mixing apples and oranges. The Lagano test has nothing to do with the latest Dr. Parkhomov's experiment of the 27th/28th February. On Tue, Mar 3, 2015 at 1:26 PM, Bob Cook frobertc...@hotmail.com wrote: Peter-- Your EGO-OUT report by Axil-Dixit sounds like it was written by Axil Axil who reports frequently on Vortex-l. Axil-Dixit's comments about the non-participating role of Ni in the Ni reaction is *NOT* borne out by the change of isotopic concentration measured in the Lugano Hot Cat test. Bob Cook - Original Message - *From:* Peter Gluck peter.gl...@gmail.com *To:* Arik El Boher elboh...@missouri.edu ; Bo Hoistadt bo.hois...@physics.uu.se ; Brian Ahern ahern_br...@msn.com ; CMNS c...@googlegroups.com ; Dagmar Kuhn dagmar.k...@gmx.de ; doug marker dsmar...@gmail.com ; Dr. Braun Tibor br...@mail.iif.hu ; eCatNews p...@ecatnews.com ; Gabriel Moagar-Poladian gamo...@yahoo.com ; Gary g...@garywright.com ; Haiko Lietz h...@haikolietz.de ; jeff aries arias...@aol.com ; Lewan Mats mats.le...@nyteknik.se ; Nicolaie N. Vlad nicolaienv...@gmail.com ; Peter Mobberley petermobber...@hotmail.com ; Pierre Clauzon pierre.clau...@orange.fr ; Roberto Germano germ...@promete.it ; Roy Virgilio r.virgi...@gmail.com ; Sunwon Park swp...@kaist.ac.kr ; vlad v...@zpenergy.com ; VORTEX vortex-l@eskimo.com ; Mark Tsirlin tsirlin.m...@hotmail.com ; Steve Katinski steve...@aol.com ; David Daggett david.l.dagg...@gmail.com ; Valerio Ciampoli v.ciamp...@gmail.com ; Peter Bjorkbom peter.bjork...@neofire.com ; Peter Schlosser schloss...@t-online.de *Sent:* Tuesday, March 03, 2015 9:55 AM *Subject:* [Vo]:diversity, one of the 6 pillars of LENR Dear Friends, Daily News focused on the Hot Cat, Axil's explanation and a few thoughts about unity or diversity in LENR-.all here: http://egooutpeters.blogspot.ro/2015/03/seeking-truth-and-power-of-lenr.html New replications at the horizon. Murphy, you never sleep? Peter -- Dr. Peter Gluck Cluj, Romania http://egooutpeters.blogspot.com
Re: [Vo]:diversity, one of the 6 pillars of LENR
I said... *There is now experimental analysis that discounts that the nickel powder has contributed any power to the LENR reaction. From a theoretical standpoint, this could be explained by the lack of proper sized particles used in the experiment and also the lack of tubercles on the surface of any nickel particle no matter its size.* * This may mean that there has been no value added to the LENR reaction from Parkhomov type nickel particles: these particles are LENR inert. For Parkhomov, his LENR+ reaction is only carried by Dynamic NAE.* On Tue, Mar 3, 2015 at 5:09 PM, Bob Cook frobertc...@hotmail.com wrote: Axil-- I may be mixing golden delicious and red delicious apples, but I do not think I have mixed up oranges with respect to either the Lugano test or Parknomov's test. You may not recognize an apple when you see one(: Both the tests in question use an alumina container, nickel...as a fuel, add heat via electrical circuits etc. As far as I know, they may both have used Li as well as a catalyst or fuel. The reaction temperature seems to be in the same ballpark for both tests. And hydrogen seems to be involved in each test. How do you think the two experiments differ in significant design aspects that are documented? Maybe I would agree with you, if I understand the differences you perceive based on reported facts from the respective tests. For example, do you know of changes or lack thereof in the Ni isotope concentrations resulting from Parkhomov's test? Bob Cook - Original Message - *From:* Axil Axil janap...@gmail.com *To:* vortex-l vortex-l@eskimo.com *Sent:* Tuesday, March 03, 2015 1:43 PM *Subject:* Re: [Vo]:diversity, one of the 6 pillars of LENR Bob, Your mixing apples and oranges. The Lagano test has nothing to do with the latest Dr. Parkhomov's experiment of the 27th/28th February. On Tue, Mar 3, 2015 at 1:26 PM, Bob Cook frobertc...@hotmail.com wrote: Peter-- Your EGO-OUT report by Axil-Dixit sounds like it was written by Axil Axil who reports frequently on Vortex-l. Axil-Dixit's comments about the non-participating role of Ni in the Ni reaction is *NOT* borne out by the change of isotopic concentration measured in the Lugano Hot Cat test. Bob Cook - Original Message - *From:* Peter Gluck peter.gl...@gmail.com *To:* Arik El Boher elboh...@missouri.edu ; Bo Hoistadt bo.hois...@physics.uu.se ; Brian Ahern ahern_br...@msn.com ; CMNS c...@googlegroups.com ; Dagmar Kuhn dagmar.k...@gmx.de ; doug marker dsmar...@gmail.com ; Dr. Braun Tibor br...@mail.iif.hu ; eCatNews p...@ecatnews.com ; Gabriel Moagar-Poladian gamo...@yahoo.com ; Gary g...@garywright.com ; Haiko Lietz h...@haikolietz.de ; jeff aries arias...@aol.com ; Lewan Mats mats.le...@nyteknik.se ; Nicolaie N. Vlad nicolaienv...@gmail.com ; Peter Mobberley petermobber...@hotmail.com ; Pierre Clauzon pierre.clau...@orange.fr ; Roberto Germano germ...@promete.it ; Roy Virgilio r.virgi...@gmail.com ; Sunwon Park swp...@kaist.ac.kr ; vlad v...@zpenergy.com ; VORTEX vortex-l@eskimo.com ; Mark Tsirlin tsirlin.m...@hotmail.com ; Steve Katinski steve...@aol.com ; David Daggett david.l.dagg...@gmail.com ; Valerio Ciampoli v.ciamp...@gmail.com ; Peter Bjorkbom peter.bjork...@neofire.com ; Peter Schlosser schloss...@t-online.de *Sent:* Tuesday, March 03, 2015 9:55 AM *Subject:* [Vo]:diversity, one of the 6 pillars of LENR Dear Friends, Daily News focused on the Hot Cat, Axil's explanation and a few thoughts about unity or diversity in LENR-.all here: http://egooutpeters.blogspot.ro/2015/03/seeking-truth-and-power-of-lenr.html New replications at the horizon. Murphy, you never sleep? Peter -- Dr. Peter Gluck Cluj, Romania http://egooutpeters.blogspot.com
Re: [Vo]:diversity, one of the 6 pillars of LENR
I believe that the reactor would need to run for some time like it did at Lagano for nuclear changes to show up. Maybe the Russian experiment that produced XP ran long enough to show changes. On Wed, Mar 4, 2015 at 12:59 AM, Bob Cook frobertc...@hotmail.com wrote: Axil and Bob-- You both seem to ignore the statement from the Lugano experiment that the Ni isotopic concentrations changed during the reaction. It would be nice to get an isotopic analysis of the MFMP and the Parkhomov experiment's Ni powder available after the experiment to see if there are changes from normal Ni. I am not sure either the Parkhomov nor the MFMP test have good evidence of a nuclear reaction with a change in nuclear species or total mass of the the system. Without an evident mass-to-energy conversion, what is the source of the explosive energy release in the two experiments? I do not consider either experiment has sufficient time producing XH to be indicative of LENR. That is not to say the two experimental set-ups have no potential for producing excess heat, if properly controlled. ( I would agree that there seemed to be a start of an excess heat reaction prior to the bangs, however the extent of this production of excess heat was not very long. ) Bob - Original Message - *From:* Bob Higgins rj.bob.higg...@gmail.com *To:* vortex-l@eskimo.com *Sent:* Tuesday, March 03, 2015 9:23 PM *Subject:* Re: [Vo]:diversity, one of the 6 pillars of LENR See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air
Re: [Vo]:diversity, one of the 6 pillars of LENR
This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. Thanks for your first hand observation. Doesn't your observation mean that the MFMP BANG was a LENR event since the fuel residue between Lagano and the bang are affected in the same way? Without the bang, the fuel is unchanged. I believe that I had seen that fuel difference reported on facebook or ECat news. On Wed, Mar 4, 2015 at 12:23 AM, Bob Higgins rj.bob.higg...@gmail.com wrote: See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the end, but it is there in tiny quantities and will be burned out of the Ni before 700C. The Ni oxide is easy to form and easy to remove in hot H2. The 5 9's part is irrelevent in the reaction as long there were no significant poisons
Re: [Vo]:diversity, one of the 6 pillars of LENR
Axil, what you are describing as proper sized and tubercles are applicable to Rossi's low temperature catalyzed Ni fuel. This is not what was used in the HotCat or Parkhomov experiment. SEM images of the Ni core from the MFMP experiment (Bang!) show that early on the Ni particles are completely reduced of oxide by the evolved hydrogen and by 300C, they are sintering into a sparse 3D web like structure. Then above 900C, the released Li-Al alloy molten metal is wetting to the Ni and actually dissolving the fine features while completely coating the Ni. This coating is a Li-Al-Ni-H alloy and this is likely a new modality of LENR with Ni inside liquid metal and with the hydrogen ions in the liquid metal. The iron in the Lugano experiment is a known catalyst to make LiAlH4 decompose at a lower temperature. That is probably why the Lugano HotCat worked better at a lower temperature than Parkhomov (the Lugano temperatures were significantly off, with the 1410C measurement probably ~1130C; I can send you the paper if you want). This also decreases that calculated COP by at least 20% which is getting closer to Parkhomov. Lugano and Parkhomov are commensurate. Rossi's low temperature eCat catalyzed fuel is different and the reaction there is gas phase. On Tue, Mar 3, 2015 at 3:18 PM, Axil Axil janap...@gmail.com wrote: I said... *There is now experimental analysis that discounts that the nickel powder has contributed any power to the LENR reaction. From a theoretical standpoint, this could be explained by the lack of proper sized particles used in the experiment and also the lack of tubercles on the surface of any nickel particle no matter its size.* * This may mean that there has been no value added to the LENR reaction from Parkhomov type nickel particles: these particles are LENR inert. For Parkhomov, his LENR+ reaction is only carried by Dynamic NAE.*
Re: [Vo]:diversity, one of the 6 pillars of LENR
Axil, have you looked at the SEM images (courtesy of Ed Storms) of the Ni from the MFMP reactor? https://drive.google.com/folderview?id=0B5Pc25a4cOM2fllFSWpFNVJoUlIxbERhRTE2M2FTY0s3TU9sZ2FsVG5wMGdodlE2ZW1JMVEusp=sharing On Tue, Mar 3, 2015 at 4:02 PM, Axil Axil janap...@gmail.com wrote: On Tue, Mar 3, 2015 at 5:40 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, what you are describing as proper sized and tubercles are applicable to Rossi's low temperature catalyzed Ni fuel. For a temperature of 1200C, the proper size is about 2 microns give or take. This is not what was used in the HotCat or Parkhomov experiment. SEM images of the Ni core from the MFMP experiment (Bang!) show that early on the Ni particles are completely reduced of oxide by the evolved hydrogen and by 300C, they are sintering into a sparse 3D web like structure. Page 43 figure 2 of the Lagano report shows a particle with tubercles. The other has been melted. Then above 900C, the released Li-Al alloy molten metal is wetting to the Ni and actually dissolving the fine features while completely coating the Ni. This coating is a Li-Al-Ni-H alloy and this is likely a new modality of LENR with Ni inside liquid metal and with the hydrogen ions in the liquid metal. There is no experimental proof of this statement. The iron in the Lugano experiment is a known catalyst to make LiAlH4 decompose at a lower temperature. true That is probably why the Lugano HotCat worked better at a lower temperature than Parkhomov (the Lugano temperatures were significantly off, with the 1410C measurement probably ~1130C; I can send you the paper if you want). This also decreases that calculated COP by at least 20% which is getting closer to Parkhomov. Key to my point, Lugano demo worked better than the Parkhomov system because Rossi's nickel particles are LENR reaction proven. Parkhomov nickel did not work as stated by Parkhomov's own experimental analysis. Lugano and Parkhomov are commensurate. Rossi's low temperature eCat catalyzed fuel is different and the reaction there is gas phase. Rossi's nickel powder looks the same over all his applications.
Re: [Vo]:diversity, one of the 6 pillars of LENR
In my version of the experiment, I plan to have samples of temperature, pressure, input current and voltage, radiation count and gamma spectrum, and then I will collect the product gas at the end for offline analysis. Of course the Ni ash will also be collected for examination. This, plus the existing papers on LiAlH4 decomposition will go a long way in understanding what is going on. I will be able to stop the experiment at any point and gather the gas and analyze the ash. I am privileged to discuss your first hand results with you. . As an experimenter you have a unchallengeable claim on the truth. Thanks. It is interesting that you will now work with LiAlH4. On Wed, Mar 4, 2015 at 12:23 AM, Bob Higgins rj.bob.higg...@gmail.com wrote: See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the end, but it is there in tiny quantities and will be burned out of the Ni before 700C. The Ni oxide is easy to form and easy to remove in hot H2. The 5 9's part is irrelevent in the reaction as long there were no significant poisons present. Rossi either used it because he had it or used it just to be sure what he started with. To really know how the chemistry of the fuel evolves with time and temperature is to run a series of experiments that
Re: [Vo]:diversity, one of the 6 pillars of LENR
Axil and Bob-- You both seem to ignore the statement from the Lugano experiment that the Ni isotopic concentrations changed during the reaction. It would be nice to get an isotopic analysis of the MFMP and the Parkhomov experiment's Ni powder available after the experiment to see if there are changes from normal Ni. I am not sure either the Parkhomov nor the MFMP test have good evidence of a nuclear reaction with a change in nuclear species or total mass of the the system. Without an evident mass-to-energy conversion, what is the source of the explosive energy release in the two experiments? I do not consider either experiment has sufficient time producing XH to be indicative of LENR. That is not to say the two experimental set-ups have no potential for producing excess heat, if properly controlled. ( I would agree that there seemed to be a start of an excess heat reaction prior to the bangs, however the extent of this production of excess heat was not very long. ) Bob - Original Message - From: Bob Higgins To: vortex-l@eskimo.com Sent: Tuesday, March 03, 2015 9:23 PM Subject: Re: [Vo]:diversity, one of the 6 pillars of LENR See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process
Re: [Vo]:diversity, one of the 6 pillars of LENR
By the way, Nicholas Cafarelli explained this to me. On Wed, Mar 4, 2015 at 12:57 AM, Axil Axil janap...@gmail.com wrote: There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. https://www.youtube.com/watch?v=6zurHSq4CB4 This video shows how a super critical medium produces nanoparticles from dissolved ionic substances when there is a super critical phase transition caused by cooling the super critical medium so that the dissolved solids nucleate and form nanoparticles. Both dissolved Lithium, aluminum, and hydrides will nucleate and form nanoparticle in a cooled region of the supercritical hydrogen gas. On Wed, Mar 4, 2015 at 12:23 AM, Bob Higgins rj.bob.higg...@gmail.com wrote: See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the end, but it is there in tiny quantities and will be burned out of the Ni before 700C. The Ni oxide is easy to form and easy to remove in hot H2. The 5 9's part is irrelevent in the reaction as long there were no significant poisons present.
Re: [Vo]:diversity, one of the 6 pillars of LENR
Regarding: I believe that I had seen that fuel difference reported on facebook or ECat news. This is it. https://www.youtube.com/watch?v=XjWqx-BE4p0feature=youtu.be On Wed, Mar 4, 2015 at 1:17 AM, Axil Axil janap...@gmail.com wrote: This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. Thanks for your first hand observation. Doesn't your observation mean that the MFMP BANG was a LENR event since the fuel residue between Lagano and the bang are affected in the same way? Without the bang, the fuel is unchanged. I believe that I had seen that fuel difference reported on facebook or ECat news. On Wed, Mar 4, 2015 at 12:23 AM, Bob Higgins rj.bob.higg...@gmail.com wrote: See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the
Re: [Vo]:diversity, one of the 6 pillars of LENR
On Tue, Mar 3, 2015 at 5:40 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, what you are describing as proper sized and tubercles are applicable to Rossi's low temperature catalyzed Ni fuel. For a temperature of 1200C, the proper size is about 2 microns give or take. This is not what was used in the HotCat or Parkhomov experiment. SEM images of the Ni core from the MFMP experiment (Bang!) show that early on the Ni particles are completely reduced of oxide by the evolved hydrogen and by 300C, they are sintering into a sparse 3D web like structure. Page 43 figure 2 of the Lagano report shows a particle with tubercles. The other has been melted. Then above 900C, the released Li-Al alloy molten metal is wetting to the Ni and actually dissolving the fine features while completely coating the Ni. This coating is a Li-Al-Ni-H alloy and this is likely a new modality of LENR with Ni inside liquid metal and with the hydrogen ions in the liquid metal. There is no experimental proof of this statement. The iron in the Lugano experiment is a known catalyst to make LiAlH4 decompose at a lower temperature. true That is probably why the Lugano HotCat worked better at a lower temperature than Parkhomov (the Lugano temperatures were significantly off, with the 1410C measurement probably ~1130C; I can send you the paper if you want). This also decreases that calculated COP by at least 20% which is getting closer to Parkhomov. Key to my point, Lugano demo worked better than the Parkhomov system because Rossi's nickel particles are LENR reaction proven. Parkhomov nickel did not work as stated by Parkhomov's own experimental analysis. Lugano and Parkhomov are commensurate. Rossi's low temperature eCat catalyzed fuel is different and the reaction there is gas phase. Rossi's nickel powder looks the same over all his applications.
Re: [Vo]:diversity, one of the 6 pillars of LENR
Yes, that is correct. We do not have an SEM of Parkhomov's Ni particles. You don't know that they were not similar to MFMP's. However, the same thing happened to Parkhomov's particles as the MFMP particles - they were covered with liquid Li-Al-Ni-H at the time of the reaction and the fine features were substantially dissolved giving the Li-Al-Ni-H its 4% Ni. This tends to equalize bigger and smaller particles. Parkhomov's choice of Ni powder seemed to have worked. He didn't get quite the COP claimed by the Lugano team for the HotCat (but the Lungano numbers appear to be wrong too high). In the Lugano case, look on page 43 Figure 2 - it is almost identical to the micrographs of MFMP, and MFMP was replicating Parkhomov. It is a pretty compelling case that all 3 experiments were commensurate at the core, save for some iron particles in the HotCat. On Tue, Mar 3, 2015 at 4:21 PM, Axil Axil janap...@gmail.com wrote: I have no problem with the surface features of the MFMP nickel powder. The comparison was between Lagano and the latest Dr. Parkhomov's experiment of the 27th/28th February. Where is the micrograph of that Russian powder? Your mixing apples and oranges. On Tue, Mar 3, 2015 at 6:15 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, have you looked at the SEM images (courtesy of Ed Storms) of the Ni from the MFMP reactor? https://drive.google.com/folderview?id=0B5Pc25a4cOM2fllFSWpFNVJoUlIxbERhRTE2M2FTY0s3TU9sZ2FsVG5wMGdodlE2ZW1JMVEusp=sharing On Tue, Mar 3, 2015 at 4:02 PM, Axil Axil janap...@gmail.com wrote: On Tue, Mar 3, 2015 at 5:40 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, what you are describing as proper sized and tubercles are applicable to Rossi's low temperature catalyzed Ni fuel. For a temperature of 1200C, the proper size is about 2 microns give or take. This is not what was used in the HotCat or Parkhomov experiment. SEM images of the Ni core from the MFMP experiment (Bang!) show that early on the Ni particles are completely reduced of oxide by the evolved hydrogen and by 300C, they are sintering into a sparse 3D web like structure. Page 43 figure 2 of the Lagano report shows a particle with tubercles. The other has been melted. Then above 900C, the released Li-Al alloy molten metal is wetting to the Ni and actually dissolving the fine features while completely coating the Ni. This coating is a Li-Al-Ni-H alloy and this is likely a new modality of LENR with Ni inside liquid metal and with the hydrogen ions in the liquid metal. There is no experimental proof of this statement. The iron in the Lugano experiment is a known catalyst to make LiAlH4 decompose at a lower temperature. true That is probably why the Lugano HotCat worked better at a lower temperature than Parkhomov (the Lugano temperatures were significantly off, with the 1410C measurement probably ~1130C; I can send you the paper if you want). This also decreases that calculated COP by at least 20% which is getting closer to Parkhomov. Key to my point, Lugano demo worked better than the Parkhomov system because Rossi's nickel particles are LENR reaction proven. Parkhomov nickel did not work as stated by Parkhomov's own experimental analysis. Lugano and Parkhomov are commensurate. Rossi's low temperature eCat catalyzed fuel is different and the reaction there is gas phase. Rossi's nickel powder looks the same over all his applications.
Re: [Vo]:diversity, one of the 6 pillars of LENR
I have no problem with the surface features of the MFMP nickel powder. The comparison was between Lagano and the latest Dr. Parkhomov's experiment of the 27th/28th February. Where is the micrograph of that Russian powder? Your mixing apples and oranges. On Tue, Mar 3, 2015 at 6:15 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, have you looked at the SEM images (courtesy of Ed Storms) of the Ni from the MFMP reactor? https://drive.google.com/folderview?id=0B5Pc25a4cOM2fllFSWpFNVJoUlIxbERhRTE2M2FTY0s3TU9sZ2FsVG5wMGdodlE2ZW1JMVEusp=sharing On Tue, Mar 3, 2015 at 4:02 PM, Axil Axil janap...@gmail.com wrote: On Tue, Mar 3, 2015 at 5:40 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, what you are describing as proper sized and tubercles are applicable to Rossi's low temperature catalyzed Ni fuel. For a temperature of 1200C, the proper size is about 2 microns give or take. This is not what was used in the HotCat or Parkhomov experiment. SEM images of the Ni core from the MFMP experiment (Bang!) show that early on the Ni particles are completely reduced of oxide by the evolved hydrogen and by 300C, they are sintering into a sparse 3D web like structure. Page 43 figure 2 of the Lagano report shows a particle with tubercles. The other has been melted. Then above 900C, the released Li-Al alloy molten metal is wetting to the Ni and actually dissolving the fine features while completely coating the Ni. This coating is a Li-Al-Ni-H alloy and this is likely a new modality of LENR with Ni inside liquid metal and with the hydrogen ions in the liquid metal. There is no experimental proof of this statement. The iron in the Lugano experiment is a known catalyst to make LiAlH4 decompose at a lower temperature. true That is probably why the Lugano HotCat worked better at a lower temperature than Parkhomov (the Lugano temperatures were significantly off, with the 1410C measurement probably ~1130C; I can send you the paper if you want). This also decreases that calculated COP by at least 20% which is getting closer to Parkhomov. Key to my point, Lugano demo worked better than the Parkhomov system because Rossi's nickel particles are LENR reaction proven. Parkhomov nickel did not work as stated by Parkhomov's own experimental analysis. Lugano and Parkhomov are commensurate. Rossi's low temperature eCat catalyzed fuel is different and the reaction there is gas phase. Rossi's nickel powder looks the same over all his applications.
Re: [Vo]:diversity, one of the 6 pillars of LENR
I meant exactly what I said. Do I have justification? Yes. The first is that Parkhomov's experiment appears to have worked and I don't' think he made a specific effort to match the Lugano powder size. Second, the Ni is dissolving into the Li-Al-H liquid metal at that temperature, removing the fine features of the carbonyl Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. On Tue, Mar 3, 2015 at 5:05 PM, Axil Axil janap...@gmail.com wrote: What does this mean... May mean that the specific nickel powder Dr Parkhomov first used is not so important On Tue, Mar 3, 2015 at 6:45 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Yes, that is correct. We do not have an SEM of Parkhomov's Ni particles. You don't know that they were not similar to MFMP's. However, the same thing happened to Parkhomov's particles as the MFMP particles - they were covered with liquid Li-Al-Ni-H at the time of the reaction and the fine features were substantially dissolved giving the Li-Al-Ni-H its 4% Ni. This tends to equalize bigger and smaller particles. Parkhomov's choice of Ni powder seemed to have worked. He didn't get quite the COP claimed by the Lugano team for the HotCat (but the Lungano numbers appear to be wrong too high). In the Lugano case, look on page 43 Figure 2 - it is almost identical to the micrographs of MFMP, and MFMP was replicating Parkhomov. It is a pretty compelling case that all 3 experiments were commensurate at the core, save for some iron particles in the HotCat. On Tue, Mar 3, 2015 at 4:21 PM, Axil Axil janap...@gmail.com wrote: I have no problem with the surface features of the MFMP nickel powder. The comparison was between Lagano and the latest Dr. Parkhomov's experiment of the 27th/28th February. Where is the micrograph of that Russian powder? Your mixing apples and oranges. On Tue, Mar 3, 2015 at 6:15 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, have you looked at the SEM images (courtesy of Ed Storms) of the Ni from the MFMP reactor? https://drive.google.com/folderview?id=0B5Pc25a4cOM2fllFSWpFNVJoUlIxbERhRTE2M2FTY0s3TU9sZ2FsVG5wMGdodlE2ZW1JMVEusp=sharing On Tue, Mar 3, 2015 at 4:02 PM, Axil Axil janap...@gmail.com wrote: On Tue, Mar 3, 2015 at 5:40 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, what you are describing as proper sized and tubercles are applicable to Rossi's low temperature catalyzed Ni fuel. For a temperature of 1200C, the proper size is about 2 microns give or take. This is not what was used in the HotCat or Parkhomov experiment. SEM images of the Ni core from the MFMP experiment (Bang!) show that early on the Ni particles are completely reduced of oxide by the evolved hydrogen and by 300C, they are sintering into a sparse 3D web like structure. Page 43 figure 2 of the Lagano report shows a particle with tubercles. The other has been melted. Then above 900C, the released Li-Al alloy molten metal is wetting to the Ni and actually dissolving the fine features while completely coating the Ni. This coating is a Li-Al-Ni-H alloy and this is likely a new modality of LENR with Ni inside liquid metal and with the hydrogen ions in the liquid metal. There is no experimental proof of this statement. The iron in the Lugano experiment is a known catalyst to make LiAlH4 decompose at a lower temperature. true That is probably why the Lugano HotCat worked better at a lower temperature than Parkhomov (the Lugano temperatures were significantly off, with the 1410C measurement probably ~1130C; I can send you the paper if you want). This also decreases that calculated COP by at least 20% which is getting closer to Parkhomov. Key to my point, Lugano demo worked better than the Parkhomov system because Rossi's nickel particles are LENR reaction proven. Parkhomov nickel did not work as stated by Parkhomov's own experimental analysis. Lugano and Parkhomov are commensurate. Rossi's low temperature eCat catalyzed fuel is different and the reaction there is gas phase. Rossi's nickel powder looks the same over all his applications.
Re: [Vo]:diversity, one of the 6 pillars of LENR
On Tue, Mar 3, 2015 at 7:20 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: I meant exactly what I said. Do I have justification? Yes. The first is that Parkhomov's experiment appears to have worked and I don't' think he made a specific effort to match the Lugano powder size. Yes the powder does not work. Second, the Ni is dissolving into the Li-Al-H liquid metal at that temperature, removing the fine features of the carbonyl Ni. Rossi says that his nickel is 5 9s pure. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure.
Re: [Vo]:diversity, one of the 6 pillars of LENR
What does this mean... May mean that the specific nickel powder Dr Parkhomov first used is not so important On Tue, Mar 3, 2015 at 6:45 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Yes, that is correct. We do not have an SEM of Parkhomov's Ni particles. You don't know that they were not similar to MFMP's. However, the same thing happened to Parkhomov's particles as the MFMP particles - they were covered with liquid Li-Al-Ni-H at the time of the reaction and the fine features were substantially dissolved giving the Li-Al-Ni-H its 4% Ni. This tends to equalize bigger and smaller particles. Parkhomov's choice of Ni powder seemed to have worked. He didn't get quite the COP claimed by the Lugano team for the HotCat (but the Lungano numbers appear to be wrong too high). In the Lugano case, look on page 43 Figure 2 - it is almost identical to the micrographs of MFMP, and MFMP was replicating Parkhomov. It is a pretty compelling case that all 3 experiments were commensurate at the core, save for some iron particles in the HotCat. On Tue, Mar 3, 2015 at 4:21 PM, Axil Axil janap...@gmail.com wrote: I have no problem with the surface features of the MFMP nickel powder. The comparison was between Lagano and the latest Dr. Parkhomov's experiment of the 27th/28th February. Where is the micrograph of that Russian powder? Your mixing apples and oranges. On Tue, Mar 3, 2015 at 6:15 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, have you looked at the SEM images (courtesy of Ed Storms) of the Ni from the MFMP reactor? https://drive.google.com/folderview?id=0B5Pc25a4cOM2fllFSWpFNVJoUlIxbERhRTE2M2FTY0s3TU9sZ2FsVG5wMGdodlE2ZW1JMVEusp=sharing On Tue, Mar 3, 2015 at 4:02 PM, Axil Axil janap...@gmail.com wrote: On Tue, Mar 3, 2015 at 5:40 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: Axil, what you are describing as proper sized and tubercles are applicable to Rossi's low temperature catalyzed Ni fuel. For a temperature of 1200C, the proper size is about 2 microns give or take. This is not what was used in the HotCat or Parkhomov experiment. SEM images of the Ni core from the MFMP experiment (Bang!) show that early on the Ni particles are completely reduced of oxide by the evolved hydrogen and by 300C, they are sintering into a sparse 3D web like structure. Page 43 figure 2 of the Lagano report shows a particle with tubercles. The other has been melted. Then above 900C, the released Li-Al alloy molten metal is wetting to the Ni and actually dissolving the fine features while completely coating the Ni. This coating is a Li-Al-Ni-H alloy and this is likely a new modality of LENR with Ni inside liquid metal and with the hydrogen ions in the liquid metal. There is no experimental proof of this statement. The iron in the Lugano experiment is a known catalyst to make LiAlH4 decompose at a lower temperature. true That is probably why the Lugano HotCat worked better at a lower temperature than Parkhomov (the Lugano temperatures were significantly off, with the 1410C measurement probably ~1130C; I can send you the paper if you want). This also decreases that calculated COP by at least 20% which is getting closer to Parkhomov. Key to my point, Lugano demo worked better than the Parkhomov system because Rossi's nickel particles are LENR reaction proven. Parkhomov nickel did not work as stated by Parkhomov's own experimental analysis. Lugano and Parkhomov are commensurate. Rossi's low temperature eCat catalyzed fuel is different and the reaction there is gas phase. Rossi's nickel powder looks the same over all his applications.
Re: [Vo]:diversity, one of the 6 pillars of LENR
Inline below... On Tue, Mar 3, 2015 at 5:34 PM, Axil Axil janap...@gmail.com wrote: On Tue, Mar 3, 2015 at 7:20 PM, Bob Higgins rj.bob.higg...@gmail.com wrote: I meant exactly what I said. Do I have justification? Yes. The first is that Parkhomov's experiment appears to have worked and I don't' think he made a specific effort to match the Lugano powder size. Yes the powder does not work. The evidence says otherwise. I believe Parkhomov to be an honest man. If the XH is never reproduced, then it would be likely that it was a mistake. However, the evidence shows that what Parkhomov is doing produces features similar to Lugano HotCat and I still think the HotCat produced XH even after my emissivity analysis (paper written). Second, the Ni is dissolving into the Li-Al-H liquid metal at that temperature, removing the fine features of the carbonyl Ni. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the end, but it is there in tiny quantities and will be burned out of the Ni before 700C. The Ni oxide is easy to form and easy to remove in hot H2. The 5 9's part is irrelevent in the reaction as long there were no significant poisons present. Rossi either used it because he had it or used it just to be sure what he started with.
Re: [Vo]:diversity, one of the 6 pillars of LENR
The evidence says otherwise. I believe Parkhomov to be an honest man. If the XH is never reproduced, then it would be likely that it was a mistake. However, the evidence shows that what Parkhomov is doing produces features similar to Lugano HotCat and I still think the HotCat produced XH even after my emissivity analysis (paper written). One of the possible mechanisms that is generated by the nickel particles is the establishment of a Bose Einstein condensate from a very early stage within the polariton soliton ensemble. The lack of functional nickel micro particles might be the reason why a decreasing heater resistance is not seen in recent Lugano replication attempts as has been seen in the Lugano test. This lack of condensate development may be causing instability in LENR power production from the dynamic NAE produced by nano-particle aggregation. A soliton BEC would distribute LENR based nuclear power evenly over all Nuclear active Sites (NAE) because of quantum mechanical entanglement of the solitons. When we see that the resistance of the heater coils is reduced to a third of normal, then we know that a global BEC is in place...that BEC will ensure that power is distributed isothermally by BEC based super-fluidity. A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the end, but it is there in tiny quantities and will be burned out of the Ni before 700C. The Ni oxide is easy to form and easy to remove in hot H2. The 5 9's part is irrelevent in the reaction as long there were no significant poisons present. Rossi either used it because he had it or used it just to be sure what he started with. To really know how the chemistry of the fuel evolves with time and temperature is to run a series of experiments that test the fuel at regular temperature steps by stopping the experiment at those temperature snapshots and do an chemical analysis of the fuel as it existed at that particular temperature. This chemical evolutionary process is complicated and experiment is more determinative than analysis.
Re: [Vo]:diversity, one of the 6 pillars of LENR
See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the end, but it is there in tiny quantities and will be burned out of the Ni before 700C. The Ni oxide is easy to form and easy to remove in hot H2. The 5 9's part is irrelevent in the reaction as long there were no significant poisons present. Rossi either used it because he had it or used it just to be sure what he started with. To really know how the chemistry of the fuel evolves with time and temperature is to run a series of experiments that test the fuel at regular temperature steps by stopping the experiment at those temperature snapshots and do an chemical analysis of the fuel as it existed at that particular temperature. This chemical evolutionary process is complicated and experiment is more determinative than analysis. In my version of the experiment, I plan to have samples of temperature, pressure, input current and voltage, radiation count and gamma spectrum, and then I will collect the product gas at the end for offline analysis. Of course the Ni ash will also be collected for examination. This, plus the existing papers on LiAlH4 decomposition will go a long way in understanding what is going on. I will be able to stop the experiment at any point and gather the gas and analyze the ash.
Re: [Vo]:diversity, one of the 6 pillars of LENR
There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. https://www.youtube.com/watch?v=6zurHSq4CB4 This video shows how a super critical medium produces nanoparticles from dissolved ionic substances when there is a super critical phase transition caused by cooling the super critical medium so that the dissolved solids nucleate and form nanoparticles. Both dissolved Lithium, aluminum, and hydrides will nucleate and form nanoparticle in a cooled region of the supercritical hydrogen gas. On Wed, Mar 4, 2015 at 12:23 AM, Bob Higgins rj.bob.higg...@gmail.com wrote: See inline ... On Tue, Mar 3, 2015 at 8:05 PM, Axil Axil janap...@gmail.com wrote: A sign that the nickel power is not working is the explosions that are occurring when the LENR reactions begin in the nano particles produced by lithium and hydrogen plasma as it cools from the high temperatures over 1100C. There is no hydrogen plasma or lithium vapor for that matter. Lithium at that pressure will not boil at the temperatures being used. If you read Langmuir's work, you will see that it takes over 2500C for any significant hydrogen molecule dissociation, and it would be much hotter still to get a hydrogen plasma. Rossi says that his nickel is 5 9s pure. 5 9's pure has no bearing on whether the Ni was dissolving. The Ni has been seen in EDX (Ed Storms' analysis of MFMP ash) the Li-Al-Ni-H solidified metal encasing the sintered Ni web. It is now known that the Ni dissolves in the liquid Li-Al-H. There was a hydrogen fire that occurred after the alumina core raptured. Much the nickel melted because of the extra heat added to the 1057C temperature where the core failure took place. The fuel was sintered into a solid block by high heat. This is completely wrong. The micrographs of the Ni ash in the MFMP experiment were the same as the Lugano Ni ash. There was no explosion in the Lugano experiment. Also, from personal experience, when Ni is heated in H2, it is fully oxide free by 250C and by 300C the sintering of the particles begins. This happens long before there was ever an explosion. Not only that, but after the explosion, the Ni core was a completely intact molded rod of sintered material. If you look at the micrographs, it would be impossible to create the sintered 3D web structure found by melting of the Ni. If the small features of the Ni are not complicit in the LENR, then it is not clear that size of the starting particles mean very much. Where is reference to this? The reference is the Lugano report and Ed Storms' micrographs of the MFMP ash. They show the Ni sintered into a 3D web with much larger dimensions. I have personally seen this sintering in my experiments with Ni powder in H2 at much lower pressure. I published a paper showing this. In the gas phase experiments, much of the fine features on the carbonyl Ni particles are maintained, sintering at touching edges. Thanks for this info. I have always thought that placing the fuel in a pile was a bad idea. The DGT idea of spreading the fuel out in three dimensions in a scaffold of nickel nanofoam would keep the nickel particles apart so that they would not sinter together. In my experience, once you coat your carbonyl Ni particles with a nano-catalyst, the catalyst can prevent substantial sintering into a solid and help leave the Ni porous. However, the carbonyl Ni particles by themselves don't want to sinter easily into a solid block - they want to sinter into a porous body naturally. The Ni particles get reduced of their oxide easily by 300C and they begin sintering into a porous web long before the reaction begins. Thus, the starting particle size bears fairly little relation to the powder configuration at 900C and above. There is no oxide. Rossi says that his nickel is 5 9s pure. Chemically that statement, is total crap. Whether Rossi started with 5 9's Ni, it was handled in air so there was an oxide. Further, the reactor was sealed with ambient air in it. The fuel also included other ingredients (Fe2O3 for example, more oxygen and iron which is a normal contaminant of Ni. Another contaminant is carbon because it is from a carbonyl process. The carbon may actually be a catalyst in the end, but it is there in tiny quantities and will be burned out of the Ni before 700C. The Ni oxide is easy to form and easy to remove in hot H2. The 5 9's part is irrelevent in the reaction as long there were no significant poisons present. Rossi either used it because he had it or used it just to be sure what he started with. To really know how the chemistry of the fuel