Dear siesta users:

I have now encounter a question: the results differ when using different number 
of core to parallel.

1 core:
siesta:  124   -33928.6003   -33928.6031   -33928.6366  0.0002 -4.1261
siesta:  125   -33928.6004   -33928.6012   -33928.6346  0.0001 -4.1251
siesta:  126   -33928.6003   -33928.6009   -33928.6344  0.0001 -4.1258

siesta: E_KS(eV) =           -33928.6012

siesta: E_KS - E_eggbox =    -33928.6012

12 core:

siesta:  123   -33928.6004   -33928.6064   -33928.6398  0.0003 -4.1246
siesta:  124   -33928.6003   -33928.6026   -33928.6360  0.0001 -4.1257
siesta:  125   -33928.6003   -33928.6018   -33928.6352  0.0001 -4.1256
siesta:  126   -33928.6004   -33928.5996   -33928.6331  0.0001 -4.1253

siesta: E_KS(eV) =           -33928.6001

siesta: E_KS - E_eggbox =    -33928.6001

The E_KS differs 0.001 eV. I think it is significant.  I think the number of 
core using to paralle only affect the speed. The results should be the same.  
Or there is something I am missing?

And I have another question: when I do the geometry optimization, which energy 
is used to calculated the force? And when I do molecular dynamics, which energy 
is used for the force?

I think the KS energy of a single point DFT calculation and the KS  energy of a 
molecular dynamics should be the same for the same structure. Am I right?

Any suggestions will be regarded.

Best

Guangping

2012-03-24



Guangping Zhang

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