I think 0.001 eV is a small quantity, and it may come from different
library when you run 1 core (serial) and 12 core (parallel).



On Sat, Mar 24, 2012 at 5:50 AM, Guangping Zhang <[email protected]> wrote:

> **
> **
> Dear siesta users:
>
> I have now encounter a question: the results differ when using different
> number of core to parallel.
>
> 1 core:
> siesta:  124   -33928.6003   -33928.6031   -33928.6366  0.0002 -4.1261
> siesta:  125   -33928.6004   -33928.6012   -33928.6346  0.0001 -4.1251
> siesta:  126   -33928.6003   -33928.6009   -33928.6344  0.0001 -4.1258
>
> siesta: E_KS(eV) =           -33928.6012
>
> siesta: E_KS - E_eggbox =    -33928.6012
>
> 12 core:
>
> siesta:  123   -33928.6004   -33928.6064   -33928.6398  0.0003 -4.1246
> siesta:  124   -33928.6003   -33928.6026   -33928.6360  0.0001 -4.1257
> siesta:  125   -33928.6003   -33928.6018   -33928.6352  0.0001 -4.1256
> siesta:  126   -33928.6004   -33928.5996   -33928.6331  0.0001 -4.1253
>
> siesta: E_KS(eV) =           -33928.6001
>
> siesta: E_KS - E_eggbox =    -33928.6001
>
> The E_KS differs 0.001 eV. I think it is significant.  I think the number
> of core using to paralle only affect the speed. The results should be the
> same.  Or there is something I am missing?
>
> And I have another question: when I do the geometry optimization, which
> energy is used to calculated the force? And when I do molecular dynamics,
> which energy is used for the force?
>
> I think the KS energy of a single point DFT calculation and the KS  energy
> of a molecular dynamics should be the same for the same structure. Am I
> right?
>
> Any suggestions will be regarded.
>
> Best
>
> Guangping
>
> 2012-03-24
> ------------------------------
>  Guangping Zhang
> **
>



-- 
Regards
Huan Tran
Department of Physics
University of Basel, Switzerland
Email: [email protected]

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