Dear siesta users,

In order to calculate the transport properties of a monolayer such as TMDs,
I want to do the geometry relaxation for a super-cell 5*7*1. I have two
different questions:

First question that, I have used the following options for the structural
relaxations of monolayer:

 # MD variables
MD.TypeOfRun        CG
MD.NumCGsteps       500
MD.MaxForceTol      0.01 eV/Ang



Should I implement “MD.VariableCell” option in the input file?

Since I have used the experimental values for the lattice vectors and the
lattice constant, it better that the relaxation is done for the unitcell
graphene, at first?



Second question that, for the geometry relaxation of a monolayer
supercell 5*7, I have generated a k-point sampling grid using, (I know
that, the following two numbers must be optimized)

%block kgrid_Monkhorst_Pack

1  0  0 0.5

0  10 0 0.5

0  0  8 0.5

%endblock kgrid_Monkhorst_Pack



Moreover, in order to do the transiesta calculation for the scattering
region including a monolayer supercell 5*5 (the transport is along z
direction), I have generated a k-point sampling grid using

%block kgrid_Monkhorst_Pack

1  0  0 0.5

0  1 0 0.5

0  0  15 0.5

%endblock kgrid_Monkhorst_Pack



And also for the electrode region, I have generated a k-point sampling
grid using

%block kgrid_Monkhorst_Pack

1  0  0 0.5

0  1 0 0.5

0  0  15 0.5

%endblock kgrid_Monkhorst_Pack

Are these correct?

It would be highly appreciated for your help and guidance.

Thanks in advance.

Best regards.

Nadia

Responder a