Dear siesta users,

In order to calculate the transport properties of a monolayer composed 2D
hexagonal lattice such as TMDs, I want to do the geometry relaxation for a
super-cell 5*7*1. I have two different questions:

First question that, I have used the following options for the structural
relaxations of monolayer:

# MD variables
MD.TypeOfRun        CG
MD.NumCGsteps       500
MD.MaxForceTol      0.01 eV/Ang



Should I implement “MD.VariableCell” option in the input file?

Since, I have used the experimental values for the lattice vectors and the
lattice constant. Is it better that the relaxation is done for a unitcell
monolayer, at first?



Second question that, for the geometry relaxation of a monolayer supercell
5*7, I have generated a k-point sampling grid using, (I know that, the
following two numbers must be optimized)

%block kgrid_Monkhorst_Pack

1  0  0 0.5

0  10 0 0.5

0  0  8 0.5

%endblock kgrid_Monkhorst_Pack



Moreover, in order to do the transiesta calculation for the scattering
region including a monolayer supercell 5*5 (the transport is along z
direction), I have generated a k-point sampling grid using

%block kgrid_Monkhorst_Pack

1  0  0 0.5

0  1 0 0.5

0  0  15 0.5

%endblock kgrid_Monkhorst_Pack



And also for the electrode region, I have generated a k-point sampling grid
using

%block kgrid_Monkhorst_Pack

1  0  0 0.5

0  1 0 0.5

0  0  15 0.5

%endblock kgrid_Monkhorst_Pack

Are these correct?

It would be highly appreciated for your help and guidance.

Thanks in advance

Best regards.

Nadia

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