This is a typical MD problem in SIESTA. It has been discussed several time
here. Kindly go through the old threads, you will find an answer. Best of
Luck.


<https://www.avast.com/sig-email?utm_medium=email&utm_source=link&utm_campaign=sig-email&utm_content=webmail&utm_term=icon>
Virus-free.
www.avast.com
<https://www.avast.com/sig-email?utm_medium=email&utm_source=link&utm_campaign=sig-email&utm_content=webmail&utm_term=link>
<#DDB4FAA8-2DD7-40BB-A1B8-4E2AA1F9FDF2>

On Wed, Jun 1, 2016 at 6:25 PM, ZARA NBSH <[email protected]> wrote:

> Dear all,
> I am new in siesta and would like to perform molecular dynamics
> calculation on graphene sheet with periodic boundary conditions and the
> total number of C atoms  200.
>
> I set the temperature to 300K, but in the output the temperature
> fluctuations are very large between 230 to 360 K.
> I copy the input file here.
> Would any one help me what is wrong in my calculations?
>
>
>
> # fdf file
>
> SystemName          graphene
> SystemLabel         c
>
> NumberOfAtoms       200
> NumberOfSpecies     1
>
> %block ChemicalSpeciesLabel
>  1  6  C
> %endblock ChemicalSpeciesLabel
>
> XC.functional GGA
> XC.authors    PBE
>
>
> LatticeConstant     2.471763457 Ang
>
> %block LatticeParameters
>      10   8.66025404     8    90.  90. 90.
> %endblock LatticeParameters
>
> AtomicCoordinatesFormat Ang
> AtomicCoordinatesAndAtomicSpecies < xyz
>
>
> %block kgrid_Monkhorst_Pack
>       1    0    0    0.0
>       0    1    0    0.0
>       0    0    1    0.0
> %endblock kgrid_Monkhorst_Pack
>
> MeshCutoff          300.0 Ry
>
> # SCF options
> MaxSCFIterations      100           # Maximum number of SCF iter
> DM.NumberPulay         3            # One Pulay every 3 iter
> DM.MixingWeight       0.25          # New DM amount for next SCF cycle
> DM.Tolerance          5.d-4         # Tolerance in maximum difference
>
> SolutionMethod        diagon        # OrderN or Diagon
> ElectronicTemperature  25 meV       # Temp. for Fermi smearing
>
>
> # structural infomation
> AtomCoorFormatOut Ang
> WriteCoorXmol T
> WriteMDXmol T
> WriteForces T
>
> # options for MD
> MD.MaxForceTol          0.01 eV/Ang
> MD.TypeOfRun    Nose
> MD.VariableCell         T
> MD.NumCGSteps           400
> MD.Broyden.History.Steps 6
> MD.Broyden.Initial.Inverse.Jacobian 1.0
>
>
> MD.InitialTimeStep 1
> MD.FinalTimeStep 2000
> MD.LengthTimeStep 1 fs
> MD.InitialTemperature 300 K
> MD.TargetTemperature 300 K
> MD.AnnealOption TemperatureAndPressure
> MD.TauRelax 100.0 fs
>
>

Responder a