You need to establish the MD.NoseMass parameter by hand. Likely, the default 
value is too large for carbon.


-Salvador


________________________________
From: [email protected] <[email protected]> on behalf of Younas 
Khan <[email protected]>
Sent: Wednesday, June 1, 2016 10:12 AM
To: siesta-l
Subject: Re: [SIESTA-L] MD simulation

This is a typical MD problem in SIESTA. It has been discussed several time 
here. Kindly go through the old threads, you will find an answer. Best of Luck.


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On Wed, Jun 1, 2016 at 6:25 PM, ZARA NBSH 
<[email protected]<mailto:[email protected]>> wrote:
Dear all,
I am new in siesta and would like to perform molecular dynamics calculation on 
graphene sheet with periodic boundary conditions and the total number of C 
atoms  200.

I set the temperature to 300K, but in the output the temperature fluctuations 
are very large between 230 to 360 K.
I copy the input file here.
Would any one help me what is wrong in my calculations?



# fdf file

SystemName          graphene
SystemLabel         c

NumberOfAtoms       200
NumberOfSpecies     1

%block ChemicalSpeciesLabel
 1  6  C
%endblock ChemicalSpeciesLabel

XC.functional GGA
XC.authors    PBE


LatticeConstant     2.471763457 Ang

%block LatticeParameters
     10   8.66025404     8    90.  90. 90.
%endblock LatticeParameters

AtomicCoordinatesFormat Ang
AtomicCoordinatesAndAtomicSpecies < xyz


%block kgrid_Monkhorst_Pack
      1    0    0    0.0
      0    1    0    0.0
      0    0    1    0.0
%endblock kgrid_Monkhorst_Pack

MeshCutoff          300.0 Ry

# SCF options
MaxSCFIterations      100           # Maximum number of SCF iter
DM.NumberPulay         3            # One Pulay every 3 iter
DM.MixingWeight       0.25          # New DM amount for next SCF cycle
DM.Tolerance          5.d-4         # Tolerance in maximum difference

SolutionMethod        diagon        # OrderN or Diagon
ElectronicTemperature  25 meV       # Temp. for Fermi smearing


# structural infomation
AtomCoorFormatOut Ang
WriteCoorXmol T
WriteMDXmol T
WriteForces T

# options for MD
MD.MaxForceTol          0.01 eV/Ang
MD.TypeOfRun    Nose
MD.VariableCell         T
MD.NumCGSteps           400
MD.Broyden.History.Steps 6
MD.Broyden.Initial.Inverse.Jacobian 1.0


MD.InitialTimeStep 1
MD.FinalTimeStep 2000
MD.LengthTimeStep 1 fs
MD.InitialTemperature 300 K
MD.TargetTemperature 300 K
MD.AnnealOption TemperatureAndPressure
MD.TauRelax 100.0 fs


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