On Mon, 20 Oct 2008 07:49:16 -5
"M. G. Devour" <[email protected]> wrote:

> I wrote:
> > > Next, if you leave the lid off you no longer have a closed system.
> > > Distilled water (and your CS), will absorb carbon dioxide from
> > > the air and form (I think it is...) carbolic acid. 
> 
> Indi replies:
> > Yes well, the idea that we actually make containers which contain
> > only H2O and silver is a misconception, as you yourself have just
> > pointed out.
> 
> Yes, but your contention that we cannot achieve any kind of effective 
> air-tight seal is quite misconcieved as well.
> 
> I've seen plastic pop bottles filled with water on a warm day in the 
> fall and left in the trunk of a car over an entire winter, collapse
> as the weather got cold, *stay* that way for months even as they
> underwent numerous freeze-thaw cycles, and return to their original
> volume the first equally warm day in the spring.
> 
> I've personally sampled home-canned fruit that was at least 20 years 
> old and still well-sealed and safely edible.
> 
> I've also designed, built and operated vacuum equipment with
> everything from O-ring seals and rough pumps to cryo-pumped
> ultra-high-vacuum systems with conflat flanges. I'm aware that there
> are detectable leak rates across various sealing materials and
> diffusion of hydrogen and helium through metals and glass.
> 
> All of my experiences back up Ken's off-the-cuff report: Although
> it's theoretically possible, in fact inevitable, that some exchange
> of gas molecules between the interior and exterior of a filled
> container will take place, at near-atmospheric pressures and for all
> practical purposes the amounts are NOT significant as long as the
> seals are functioning as they're designed.
> 
> If you are concerned about effects down in the 10^-12 range, don't 
> bother. They are not meaningful in this discussion. Nothing we do
> here is that precise, nor does it need to be.
> 
> > As I said, without proper chemical analysis one cannot be sure of
> > the exact content, and it is exceedingly unlikely that what we make
> > to start with is pure H2O and silver only, or that the solution
> > stored in simple jars will remain unchanged for very long. 
> 
> Once whatever dissolved gases included in the closed container have 
> finished doing whatever they're going to do over the first few days, 
> long term changes appear to be minimal, based on more reports than
> just Ken's. 
> 
> Given how sensitive electrical conductivity happens to be to even 
> slight changes in conditions or composition, getting two readings
> even roughly the same months apart is a pretty strong indicator that
> things haven't changed significantly. 
> 
> In our experience, that's the nature of the beast when you're talking 
> about conductivity. While the exact value of your readings may not be 
> all that close to some theoretical ideal measurement, comparative 
> readings are in fact pretty sensitive to changes.
> 
> > That is my point, and I certainly cannot yield it, I'd be lying. 
> 
> Well, you're welcome to your position, but in the absence of actual 
> experiences contradicting the rest of us, I'll take a wait-and-see 
> attitude on your assertions, okay? <grin>
> 

That's fine, but I think you may have misunderstood the nature of the
discussion. I am aware that to some it may have looked like I was
picking on Ode (Is Ode whom you call Ken, or did I misidentify someone?
I'm a bit confused about that now), but in fact there was an insistence
that I accept unproven conclusions based on rudimentary observation as
"fact", followed by a stream of defensive argument largely based on
misconceptions. I don't like to argue very much actually, but I was
compelled to do so due to certain ideas (which I will not mention,
wishing to be done with it) being presented as facts. I'd have been
happy to let it go days ago, personally, and I think If all my emails
did get through that is apparent. In short, I don't feel I was the one
"pushing" anything, I just cannot be forced to agree with things I know
are unlikely to be true. 

Anyway, I see you are trying to establish a neutral middle ground, and I
appreciate that. You're a good moderator.


> > Anyway, thanks for pointing out my misstatements. I will be more
> > careful about that in the future. Not sure if you read the whole
> > discussion though, as there was a lot of email I never got the last
> > couple of days and I have no way of knowing if all the email I sent
> > got through. I think it was Comcast's fault, but am not sure...
> 
> As near as I can tell from here, all your posts made it through, 
> including the one you re-sent when you didn't see it. (Which is 
> understandable given the circumstances.) Three people have now
> reported to me that COMCAST has once again been intermittently
> blocking messages from the list server.  
> 

Surely there is a special place in hell for comcast executives...


Cheers,
indi


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