The Canadian Gov. silver site: 
http://www.env.gov.bc.ca/epd/cpr/criteria/awqcfs.html
states basically that "solver ions are 300 times more effective then silver 
chloride
(if you salt water) and 15,000 times more effective then silver sulphide. The 
chance 
of using water with sulphide in it is small but the point is that other silver 
compounds
may be just as non-effective! As I always stress, you must know what you start 
with,
to get an effective form of silver for delivery to your body.

<snip>silver is one of the most toxic of the heavy metals to freshwater 
micro-organisms. 
<snip>
 The effect of speciation on the acute and chronic toxicity of silver was 
compared using the fathead
 minnow as the test organism. Silver sulfide, silver thiosulfate and silver 
chloride were compared to
 the silver ion, added as silver nitrate. The tests were flow-through in soft 
water at 25°C. Silver
 chloride was found to be 300 times less toxic, silver sulfide was 15,000 times 
less toxic, and silver
 thiosulfate was 17,500 times less toxic than silver nitrate.

 Most existing silver criteria, objectives or regulated amounts are not based 
on the free ionic
 monovalent ion, which is acutely toxic to aquatic life. Instead they are based 
on total silver which
 includes the metal, complexes and precipitates, all of which are very much 
less toxic than the
 monovalent ion. </snip>

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