In a message dated 12/26/00 6:03:09 AM EST, [email protected] writes:

<< Subj:     Re: CS>Research Paper available
 Date:  12/26/00 6:03:09 AM EST
 From:  [email protected] (Ivan Anderson)
 Reply-to:  [email protected]
 To:    [email protected]
 
 Thanks for the reference Frank,
 
 I found this to be a very curious document indeed.
 Firstly, the conclusion that, "High quality colloids contain a high
 percentage of silver particles [ by this the authors mean uncharged
 particles of silver metal ]. Ideally, a silver colloid would contain no
 ions." does not address the fact that ions are probably the active
 ingredient of CS.

Ivan: Apparantly they provide no supporting evidence for their conclusion.
 
 Of course, if the object of the exercise is to produce a high quality
 colloid in the literal sense of the word, then the authors may be
 correct in their conclusions. However if the object is to produce a CS
 which is most effective in its antiseptic action, then the conclusions
 drawn are irrelevant, unless a colloid, in its literal sense, fulfils
 such an outcome.

Ivan: Again, there appears to be no supporting evidence for these conclusions.
 
 The authors also mention that silver ions will ionise water, ie, break
 it apart into H+ and OH- components (the first time I have ever heard of
 this) "The negative charge of the hydroxyl ions counters the positive
 charge of the silver ions and maintains a solution of whose net charge
 is zero." which completely ignores the positive charge of the H+ ions
 which must be equal in number to the OH- hydroxyl ions from which they
 split.

Ivan: Perhaps the conceptual error here is to emphasize CONCENTRATION and not 
ACTIVITY which is the true measure of how and to what extent species 
interact. For example, it is not necessary to split apart additional water 
molecules into hydrogen and hydroxyl ions in order to change the activity of 
either ionic species, and, therefore, affect pH. This phenomenon occurs 
because it IS possible the change the environment around water molecules 
which can increase its polarity. I believe that the HVAC process which uses 
an arc to produce CS may generate many extremely small, charged CS particles 
that increase the polarization of nearby water molecules which "exposes" more 
of the positive end of the molecule which effectively raises the activity of 
H+, thus lowering pH. 
 
Roger


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