That was a nice little silver essay, thanks Ivan...

----- Original Message ----- 
From: Ivan Anderson <[email protected]>
To: <[email protected]>
Sent: Friday, March 23, 2001 4:16 AM
Subject: CS>Solubility of silver in water.


> There is a constant, but small reaction, at the silver metal/water
> interface:
> Ag + e <----> Ag+.
> Thermal currents and diffusion will dilute the concentration near this
> interface, so that in order to maintain an equilibrium more silver will
> dissolve.
> 
> http://www.burnsurgery.org/Betaweb/Modules/silver/section3.htm
> (well worth reading, if you are into silver ions)
> 'This unique physical structure, in combination with the oxygen
> atoms/molecules that are trapped in the crystal lattice, contribute to
> the enhanced solubility of the films which continue to release silver
> until the concentration in solution reached 66 mg/L a level that is 50
> to 100 times higher than is expected from typical bulk pieces of silver
> metal. Handbook of Chemistry and Physics, 55th ed., CRC Press,
> Cleveland, 1974, pp B-134.'
> 
> This passage would seem to suggest one can expect a concentration of
> 0.66 - 1.32mg/L to be eventually reached in solution.
> 
> Ivan.


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