Roger wrote:

>  Another question... Why don't the ions "plate out" on the particles
> > anyway, specially, as Frank says, the particles carry a neutral charge?
> > Silver ions do have a strong tendency to reduce back to the metal. Roger

For an ion to become a metallic particle (atom) is must take on an electron. 
Unless an electron is supplied to make the atom "whole" again, it remains an 
ion. Ions remain dispersed in the water due mutual repulsion caused by their 
"ionic charge" so would normally remain dispersed unless coerced into some 
other behavior.

An action that would force the ions to take on an electron would be to 
evaporate the water containing the ions. The electron would be supplied by an 
available anion, which must be present. When the water containing silver ions 
is evaporated, this causes the formation of silver hydroxide and/or silver 
carbonate, both of which reduce to silver oxide.

This explains why so much silver oxide is created when the water is evaporated 
from a highly ionic silver solution. The molecules of the silver oxide formed 
in this fashion are in the 1-3 nm range.


frank key


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